OXIDATION OF PHENOLIC WASTEWATER WITH GLYCOL IN SUPERCRITICAL WATER

被引:0
作者
Lv Wenyu [1 ,2 ]
Shuang Haiqing [2 ]
机构
[1] Xian Univ Sci & Technol, Minist Educ China, Key Lab Western Safe Min & Hazard Control, Xian 710054, Peoples R China
[2] Xian Univ Sci & Technol, Sch Energy Engn, Xian 710054, Peoples R China
来源
OXIDATION COMMUNICATIONS | 2015年 / 38卷 / 02期
基金
中国国家自然科学基金;
关键词
phenolic wastewater; glycol; supercritical water oxidation; phenol removal; KINETICS; MECHANISM; TOXICITY;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Phenolic wastewater is a typical kind of industrial effluents with high toxicity and poor biodegradability. Huge quantities of phenol-polluted waters are formed from many chemical operations including coking, coal gasification, oil refineries, plastics, pesticides, steel and phenolic resin production. This paper deals with treating high phenol-concentrated wastewater by supercritical water oxidation (SCWO) method. The effects of H2O2 dosage, reaction time, temperature, and concentration of glycol on removal efficiency of phenol were studied with laboratory bench-scale experiments. The results indicated that the removal process was more effective under the experimental conditions. The best removal efficiency of phenol reached 99.8%. This investigation could provide fundamental method for developing a pretreatment method of industrial phenolic wastewater with flexibility, simplicity and high activity.
引用
收藏
页码:796 / 802
页数:7
相关论文
共 20 条
[1]   Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: A short review [J].
Ahmed, Saber ;
Rasul, M. G. ;
Brown, R. ;
Hashib, M. A. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2011, 92 (03) :311-330
[2]   The treatment of phenolic wastewater using a moving bed biofilm reactor [J].
Borghei, SM ;
Hosseini, SH .
PROCESS BIOCHEMISTRY, 2004, 39 (10) :1177-1181
[3]   A reduced mechanism for methanol oxidation in supercritical water [J].
Brock, EE ;
Savage, PE ;
Barker, JR .
CHEMICAL ENGINEERING SCIENCE, 1998, 53 (05) :857-867
[4]   Comparison of the effect of phenol and its derivatives on protein and free radical formation in human erythrocytes (in vitro) [J].
Bukowska, B. ;
Michalowicz, J. ;
Krokosz, A. ;
Sicinska, P. .
BLOOD CELLS MOLECULES AND DISEASES, 2007, 39 (03) :238-244
[5]   Catechol ortho-quinones: the electrophilic compounds that form depurinating DNA adducts and could initiate cancer and other diseases [J].
Cavalieri, EL ;
Li, KM ;
Balu, N ;
Saeed, M ;
Devanesan, P ;
Higginbotham, S ;
Zhao, J ;
Gross, ML ;
Rogan, EG .
CARCINOGENESIS, 2002, 23 (06) :1071-1077
[6]   Oxidative catalysts for the transformation of phenolic pollutants: a brief review [J].
Gianfreda, Liliana ;
Iamarino, Giuseppina ;
Scelza, Rosalia ;
Rao, Maria A. .
BIOCATALYSIS AND BIOTRANSFORMATION, 2006, 24 (03) :177-187
[7]   Biodegradation of phenol in a continuous process:: comparative study of stirred tank and fluidized-bed bioreactors [J].
González, G ;
Herrera, MG ;
García, MT ;
Peña, MM .
BIORESOURCE TECHNOLOGY, 2001, 76 (03) :245-251
[8]   Adsorption of phenol from aqueous solutions using mesoporous carbon prepared by two-stage process [J].
Kennedy, L. John ;
Vijaya, J. Judith ;
Kayalvizhi, K. ;
Sekaran, G. .
CHEMICAL ENGINEERING JOURNAL, 2007, 132 (1-3) :279-287
[9]   COMBINED TREATMENT OF PHENOLIC WASTE-WATER BY WET AIR OXIDATION AND ACTIVATED-SLUDGE [J].
LIN, SH ;
CHUANG, TS .
TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1994, 44 (3-4) :243-258
[10]  
Malipatil A, 2010, OXID COMMUN, V33, P327