In-depth study of the influence of electrolyte composition on coatings prepared by plasma electrolytic oxidation of TA6V alloy

被引：27

作者：

Laveissiere, M. ^{[1
]}

Cerda, H. ^{[1
,2
]}

Roche, J. ^{[3
]}

Cassayre, L. ^{[4
]}

Arurault, L. ^{[3
]}

机构：

[1] IRT St Exupery, 3 Rue Tarfaya, F-31400 Toulouse, France

[2] Liebherr Aerosp, 408 Ave Etats Unis, F-31016 Toulouse 2, France

[3] Univ Toulouse, CIRIMAT, CNRS, UT3 Paul Sabatier, 118 Route Narbonne, F-31062 Toulouse 09, France

[4] Univ Toulouse, CNRS, Lab Genie Chim, Toulouse, France

来源：

SURFACE & COATINGS TECHNOLOGY | 2019年 / 361卷

关键词：

Titanium alloy; TA6V; Plasma electrolytic oxidation; Coating characteristics; Electrolyte species; Thermodynamic calculations; MICROARC OXIDATION; TITANIUM-ALLOY; ALUMINOSILICATE GELS; CHEMICAL-COMPOSITION; PHYSICAL-CHEMISTRY; TI-6AL-4V ALLOY; PURE TITANIUM; WEAR; CORROSION; BEHAVIOR;

D O I：

10.1016/j.surfcoat.2018.12.122

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Coatings were prepared on TA6V alloy by plasma electrolytic oxidation (PEO) using a standard electrical signal. Influence of electrolyte composition on coating characteristics was then extensively studied using four electrolytes of increasing complexity, containing KOH, Na2SiO3 and NaAlO2. The combination of SEM, GDOES, XRD characterizations on the one hand and of thermodynamic calculations on the other hand, deeply clarified coating compositions, showing in particular that they include both amorphous and crystalline phases. Amorphous phase resulted directly from the presence of silicate in solution, and was made of complex Si-based oxides difficult to clearly identify. Depending on electrolyte composition, crystalline phases in coatings included simple oxide (i.e. anatase and rutile TiO2) and/or mixed oxide (Al2TiO3), resulting from both substrate oxidation and deposition from electrolyte. Therefore, this study successfully offered an innovative approach, combining both experimental characterizations and thermodynamic calculations, to study and tune chemical characteristics of PEO coatings on TA6V.

引用

页码：50 / 62

页数：13

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