Synthesis of novel porphyrin arrays directly-linked through the meso-carbons

被引：109

作者：

Susumu, K

Shimidzu, T

Tanaka, K

Segawa, H

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,DIV MOL ENGN,SAKYO KU,KYOTO 60601,JAPAN

[2] RES DEV CORP JAPAN,PRESTO,FIELD & REACT,TOKYO,JAPAN

[3] UNIV TOKYO,GRAD SCH ARTS & SCI,DEPT CHEM,MEGURO KU,TOKYO 153,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 46期

关键词：

D O I：

10.1016/0040-4039(96)01920-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel dimeric and trimeric arrays of free-base porphyrins directly-linked through their meso-carbons without any spacer were synthesized and characterized. The significant spectral change occurred in the absorption spectra of these arrays compared with that of the reference monomer, indicating strong electronic interactions in spite of the orthogonal geometry between the adjacent porphyrins. Copyright (C) 1996 Elsevier Science Ltd

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页码：8399 / 8402

页数：4

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