Regulating Cutoff Size of Metal-Organic Frameworks by In Situ Anchoring of Poly(ethylene glycol) to Boost CO2 Capture

被引:8
作者
Wang, Dongyue [1 ,2 ]
Wang, Qiuchen [1 ,2 ]
Zheng, Wenji [1 ,2 ,3 ]
Dai, Yan [1 ,3 ]
Ruan, Xuehua [1 ,2 ]
Li, Xiangcun [1 ]
He, Gaohong [1 ,2 ,3 ]
机构
[1] Dalian Univ Technol, R&D Ctr Membrane Sci & Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China
[2] Dalian Univ Technol, Sch Chem Engn, Panjin 124221, Peoples R China
[3] Dalian Univ Technol, Panjin Inst Ind Technol, Liaoning Key Lab Chem Addit Synth & Separat, Panjin 124221, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
MIXED-MATRIX MEMBRANES; POLYAMIDE COMPOSITE MEMBRANES; POST-SYNTHETIC MODIFICATION; SEPARATION PERFORMANCE; CO2/N-2; NANOPARTICLES; SELECTIVITY; CO2/CH4; MIL-101(CR)-NH2; SERIES;
D O I
10.1021/acs.iecr.2c00303
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Pore engineering of metal-organic frameworks is essential to achieve selective sieving of gas molecules for mixed matrix membranes (MMMs). In this work, poly(ethylene glycol) diglycidyl ether (PEGDGE) small molecules were proposed to be immobilized into the cage of NH2-MIL-101(Cr) (NMIL-101) by a covalent bond. A precise adjustment in pore size of NMIL-101 was achieved through controlling PEGDGE content. The ring-opening reaction is confirmed to happen between epoxy and amino groups by Fourier transform infrared spectroscopy. CO2/N-2 selectivity increases gradually with increasing PEGDGE content, demonstrating the effective screening of the pores regulated by PEGDGE. When PEGDGE content is 20.8 wt %, the MMMs have the best gas separation performance, with a CO2 permeability of 111.6 Barrer and a CO2/N-2 selectivity of 72.8, which are increased by 31.2% and 30.8%, respectively. Specifically, compared with PEGDGE(13)(.0)/NMIL-101-based MMM without a ring-opening reaction, PEGDGE(11)(.1)@NMIL-101 presents an improvement in both CO2 permeability and selectivity, indicating the necessity of in situ anchoring of PEGDGE.
引用
收藏
页码:6650 / 6661
页数:12
相关论文
共 57 条
[1]   Application of interfacially polymerized polyamide composite membranes to isopropanol dehydration: Effect of membrane pre-treatment and temperature [J].
Albo, Jonathan ;
Wang, Jinhui ;
Tsuru, Toshinori .
JOURNAL OF MEMBRANE SCIENCE, 2014, 453 :384-393
[2]   Gas transport properties of interfacially polymerized polyamide composite membranes under different pre-treatments and temperatures [J].
Albo, Jonathan ;
Wang, Jinhui ;
Tsuru, Toshinori .
JOURNAL OF MEMBRANE SCIENCE, 2014, 449 :109-118
[3]   MIL-125(Ti) based mixed matrix membranes for CO2 separation from CH4 and N2 [J].
Anjum, M. Waqas ;
Bueken, B. ;
De Vos, D. ;
Vankelecom, Ivo F. J. .
JOURNAL OF MEMBRANE SCIENCE, 2016, 502 :21-28
[4]   Confinement of Ionic Liquids in Nanocages: Tailoring the Molecular Sieving Properties of ZIF-8 for Membrane-Based CO2 Capture [J].
Ban, Yujie ;
Li, Zhengjie ;
Li, Yanshuo ;
Peng, Yuan ;
Jin, Hua ;
Jiao, Wenmei ;
Guo, Ang ;
Wang, Po ;
Yang, Qingyuan ;
Zhong, Chongli ;
Yang, Weishen .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (51) :15483-15487
[5]   A metal-organic framework-based splitter for separating propylene from propane [J].
Cadiau, A. ;
Adil, K. ;
Bhatt, P. M. ;
Belmabkhout, Y. ;
Eddaoudi, M. .
SCIENCE, 2016, 353 (6295) :137-140
[6]   Advanced Porous Materials in Mixed Matrix Membranes [J].
Cheng, Youdong ;
Ying, Yunpan ;
Japip, Susilo ;
Jiang, Shu-Dong ;
Chung, Tai-Shung ;
Zhang, Sui ;
Zhao, Dan .
ADVANCED MATERIALS, 2018, 30 (47)
[7]   Redefining the Robeson upper bounds for CO2/CH4 and CO2/N2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity [J].
Comesana-Gandara, Bibiana ;
Chen, Jie ;
Bezzu, C. Grazia ;
Carta, Mariolino ;
Rose, Ian ;
Ferrari, Maria-Chiara ;
Esposito, Elisa ;
Fuoco, Alessio ;
Jansen, Johannes C. ;
McKeown, Neil B. .
ENERGY & ENVIRONMENTAL SCIENCE, 2019, 12 (09) :2733-2740
[8]   A Physical Entangling Strategy for Simultaneous Interior and Exterior Modification of Metal-Organic Framework with Polymers [J].
Dai, Dejun ;
Wang, Hongliang ;
Li, Conger ;
Qin, Xuedi ;
Li, Tao .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (13) :7389-7396
[9]   Large-Pore Apertures in a Series of Metal-Organic Frameworks [J].
Deng, Hexiang ;
Grunder, Sergio ;
Cordova, Kyle E. ;
Valente, Cory ;
Furukawa, Hiroyasu ;
Hmadeh, Mohamad ;
Gandara, Felipe ;
Whalley, Adam C. ;
Liu, Zheng ;
Asahina, Shunsuke ;
Kazumori, Hiroyoshi ;
O'Keeffe, Michael ;
Terasaki, Osamu ;
Stoddart, J. Fraser ;
Yaghi, Omar M. .
SCIENCE, 2012, 336 (6084) :1018-1023
[10]   Challenges and opportunities for mixed-matrix membranes for gas separation [J].
Dong, Guangxi ;
Li, Hongyu ;
Chen, Vicki .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (15) :4610-4630