2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activity

被引：10
作者：
Massoud, Alshima'a A. [1 ]
Langer, Vratislav [1 ]
Gohar, Yousry M. [2 ]
Abu-Youssef, Morsy A. M. [3 ]
Janis, Janne [4 ]
Ohrstrom, Lars [1 ]
机构：
[1] Chalmers, Dept Chem & Biol Engn, SE-41296 Gothenburg, Sweden
[2] Univ Alexandria, Dept Microbiol, Alexandria 21321, Egypt
[3] Univ Alexandria, Dept Chem, Alexandria 21321, Egypt
[4] Univ Eastern Finland, Dept Chem, FI-80101 Joensuu, Finland
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 04期
关键词：
Silver(I) compounds; 2,2 '-bipyrimidine; X-ray structure; Anti-microbial activity; COORDINATION POLYMER; CRYSTAL-STRUCTURES; MASS-SPECTROMETRY; COMPLEXES; LIGANDS; HEXAMETHYLENETETRAMINE; BURNS;
D O I：
10.1016/j.inoche.2011.01.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthesis and X-ray single crystal structure analysis of the compound {[Ag-2(mu(2)-bpym)(mu-O-NO3)(2)]}(n), (1), (where bpym = 2,2'-bipyrimidine) are presented. Compound (1) has a (6,3)-2D honeycomb structure with a tetrahedral coordination geometry around the Ag(I) ion. In contrary to the solid state structural investigation, ESI-MS for (1) in solution shows a strong peak at m/z 423.0269 which indicates that the [Ag(bpym)(2)](+) cation is dominating instead of [Ag-2(bpym))(2+). The anti-microbial activity of (1) was screened against 15 multi-drug resistant bacteria in comparison to silver(I) sulphadiazine and it showed a high activity against Burkholderia mallei which causes glanders; with a MIC value of 4 mu g/ml. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.
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收藏
页码：550 / 553
页数：4
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