A Straightforward Synthesis to Novel 1,10-Phenanthrolines with Fused Thiophene Structure

被引：2

作者：

Tuennermann, Maike ^{[1
]}

Rehsies, Pia ^{[1
]}

Floerke, Ulrich ^{[1
]}

Bauer, Matthias ^{[1
]}

机构：

[1] Paderborn Univ, Dept Chem, Warburger Str 100, D-33098 Paderborn, Germany

来源：

SYNLETT | 2018年 / 29卷 / 20期

关键词：

thiophene; 1; 10-phenanthroline; fused thiophene; semiconductor; organic solar cells; 3,4-ETHYLENEDIOXYTHIOPHENE EDOT; ELECTRON-TRANSFER; PERFORMANCE; COMPLEXES; HYDROGEN; ACCEPTOR; LIGANDS;

D O I：

10.1055/s-0037-1611022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report here a straightforward synthesis for a series of new structures with fused 1,10-phenanthroline-thiophene connection. They are synthesized with a modified Hinsberg thiophene procedure, followed by successive modification to yield several 5,7-disubstituted thieno[3,4-f][1,10] phenanthrolines, most notable thiophene-substituted compounds that could be potentially of use for organic electronics applications. For some selected examples, crystal structures were obtained, showing a nearly coplanar arrangement around the fused connection, also beneficial for an effective electron transfer in organic electronics or solar cells.

引用

页码：2638 / 2642

页数：5

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