Experimental study on detonation propagation characteristics of hydrogen-nitrous oxide at stoichiometric and fuel-lean conditions

被引:0
|
作者
Ji, Tian [1 ]
Chen, Die [1 ]
He, Ze [1 ]
Ma, Hong-Hao [1 ,2 ]
Wang, Lu-Qing [1 ]
机构
[1] Univ Sci & Technol China, CAS Key Lab Mech Behav & Design Mat LMBD, Dept Modern Mech, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Critical pressure; Nitrous oxide; Velocity deficit; Detonation cell; MINIMUM IGNITION ENERGY; FLAMMABILITY LIMITS; VELOCITY DEFICITS; FLAME SPEEDS; DELAY TIMES; SHOCK-TUBE; MIXTURES; METHANE; OXYGEN; AIR;
D O I
10.1016/j.ijhydene.2022.06.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Knowledge of detonation propagation characteristics of H-2-N2O mixtures is crucial for industrial safety and development. In this study, the detonation propagation characteristics of H-2-N2O mixtures with different equivalence ratios (phi = 0.4, 0.6, and 1.0) in three tubes (d = 14.5, 19.5, and 28.6 mm) were investigated experimentally. Some dominant chemical lengths were evaluated together with cell size and normalized average velocity. The results show that the periodic oscillation of local velocity is more intense as approaching the limits. Below the limits, the detonation fails and decays rapidly to a "low velocity" regime. The tube scale and initial pressure determine the velocity deficit and the minimum detonation velocity shows no obvious trend on the mixture composition and tube scale. Scaling analysis illustrates that the dimensionless parameter d/Delta(1) and normalized average velocity show a single exponential growth trend. Notably, the detonation tends to decay earlier at phi -1.0 than phi - 0.4 or phi - 0.6. Besides, fuel-lean mixtures (q, = 0.4 and 0.6) and stoichiometric mixtures (phi = 1.0) share similar critical pressure. It can be obtained that a linear relationship exists between the cell size and the induction length. The cell size data shows that the cell size of phi = 0.6 is the smallest, which agrees with the results of the induction length calculated. It is also demonstrated that the maximum value of heat release ratio peak is at q, = 0.6. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:25795 / 25807
页数:13
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