A new viscosity model for petroleum fluids with high asphaltenes content

被引:17
作者
Werner, A
de Hemptinne, JC
Behar, F
Behar, E
Boned, C
机构
[1] Inst Francais Petr, Dept Thermodynam & Transport Proc, F-92506 Rueil Malmaison, France
[2] Inst Francais Petr, Dept Geochem, F-92506 Rueil Malmaison, France
[3] Univ Pau & Pays Adour, High Pressure Lab, F-64000 Pau, France
关键词
viscosity; petroleum liquid; asphaltenes; model; mixing rule;
D O I
10.1016/S0378-3812(98)00252-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
A compositional model for predicting the viscosity of petroleum fluids as a function of temperature and pressure has been developed. It is based on a mixing rule that takes into account the compositional information, and on the model of Kanti et al. [1] for the dependence on pressure and temperature. The approach of Grunberg and Nissan [2] is used in order to take into account the fluids composition. Four different fractions are used: Gas, C-6-C-20, C20+ (saturates + aromatics + resins), and C20+ (asphaltenes). This model is designed so as to be valid in a large compositional range, especially for liquids containing large amounts of asphaltenes. The model of Kanti uses a single viscosity value for predicting fluid viscosity at any pressure and temperature. Its universal parameters have been fitted on a large database ranging up to 100 MPa in pressure and up to 120 degrees C in temperature. The validation of this new model on 76, so far, unpublished experimental data points of crude oils, covering a dynamic viscosity range from 2 to 23,298 mPa s, led to an absolute mean deviation of 24%, (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:319 / 341
页数:23
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