A downer reactor for short-time plasma surface modification of polymer powders

被引:43
作者
Arpagaus, C [1 ]
Sonnenfeld, AE [1 ]
von Rohr, PR [1 ]
机构
[1] ETH, Swiss Fed Inst Technol, Inst Proc Engn, CH-8092 Zurich, Switzerland
关键词
D O I
10.1002/ceat.200407045
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper introduces a plasma reactor for short-time plasma surface modification of polymer powders. This reactor type, the so-called plasma downer reactor (PDR), provides a high reaction rate, which is forced by the high gas velocity and high particle dispersion in the plasma. It combines the advantageous characteristics of the downer principle for the fluid dynamics of gas-solid phases with plasma surface modification. This work demonstrates that a very short plasma exposure time of 0.1 s effectively improves the wettability of HDPE and Co-PA powders. The water contact angles of HDPE and Co-PA powder can be reduced to 72degrees and 76degrees, respectively. The surface tensions of both polymer powders could be increased by a factor of 2 up to 43 mN/m. Water/polymer suspensions and pastes can be made without tensides.
引用
收藏
页码:87 / 94
页数:8
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