Exceptional photosensitivity of a polyoxometalate-based charge-transfer hybrid material

被引：108
作者：
Liao, Jian-Zhen [1 ,2 ]
Wu, Chen [1 ]
Wu, Xiao-Yuan [1 ]
Deng, Shui-Quan [1 ]
Lu, Can-Zhong [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 46期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; ELECTRON-TRANSFER; NAPHTHALENE DIIMIDES; DESIGN; PHOTOCHROMISM; CHROMOPHORE; SWITCHES; SYSTEMS; DONORS; FILMS;
D O I：
10.1039/c6cc02711c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unusual room-temperature light sensitivity was realized in a polyoxometalate-based hybrid material due to cooperative multicomponent molecular charge-transfer interactions taking place in this material, mainly among POMs, NDIs, and other molecules. The functional pi-acidic NDI linkers and POM clusters in the discussed hybrid material were individually designed as photosensors and electron reservoirs. To propose a photo-induced charge-transfer mechanism, EPR, XPS, UV-Vis and computational studies were carried out, and indicated the presence of active charge-transfer interactions among several of the components.
引用
收藏
页码：7394 / 7397
页数：4
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