Adsorption properties of N-tetradecyl-N,N-dimethyl-N-(2,3-epoxy propyl) ammonium chloride with inorganic salts at air/water

被引:0
|
作者
Liu, Jiawei [1 ]
Wang, Ling [1 ]
Li, Yan [1 ]
Wang, Jingui [1 ]
Yang, Xiaodeng [1 ]
机构
[1] Qilu Univ Technol, Shandong Acad Sci, Shandong Prov Key Lab Mol Engn, Jinan, Peoples R China
基金
中国国家自然科学基金;
关键词
N-alkyl-N; N-dimethyl-N-(2; 3-epoxy propyl) ammonium chloride; interface dilatation rheology; dynamic adsorption; DYNAMIC INTERFACIAL-TENSION; AIR-WATER-INTERFACE; DILATIONAL RHEOLOGY; SERUM-ALBUMIN; PENDANT DROP; PART; SURFACE; VISCOELASTICITY; COMPLEXES; BEHAVIOR;
D O I
10.1080/01932691.2020.1764851
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of N-alkyl-N,N-dimethyl-N-(2,3-epoxy propyl) ammonium chloride (C(n)EAC, n = 10, 12, 14, 16) with alkyl of decyl, dodecyl, tetradecyl, and hexadecyl were synthesized. The adsorption properties of C(n)EAC under the different temperatures, concentrations, interfacial oscillation frequencies as well as the inorganic salts (NaCl and Na2CO3) at air/water interface were investigated by interfacial dilatational rheology. The dilatational properties of C(n)EAC solutions including complex moduli, elastic moduli and viscosity moduli increased with oscillation frequency. The elastic moduli were higher than those of viscosity ones. With different hydrogen carbon length, the complex moduli of C(n)EAC showed different changing role with their concentration and temperature. Inorganic salts compressed the oppositely charges on C(n)EAC micelle surface and induced the decrease of both complex and viscosity moduli.
引用
收藏
页码:1376 / 1384
页数:9
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