Oxidation of ZrB2-SiC-Graphite Composites Under Low Oxygen Partial Pressures of 500 and 1500 Pa at 1800°C

The oxidation behavior of ZrB2-SiC-graphite composites under low oxygen partial pressures of 500 and 1500 Pa at 1800 degrees C was investigated. The phase composition and microstructure of the oxidized scale were characterized using TEM, SEM, XRD, XPS, EDS. The analytical results indicated that a low oxygen partial pressure had a remarkable effect on the oxidation mechanism of ZrB2-SiC-graphite composites. When oxidized at 1500 Pa, the oxidation kinetics was controlled by the rate of oxygen diffusion into the composite. When the composite was oxidized at 500 Pa, control of the oxidation kinetics changed from the rate of oxygen diffusion to the rate of the oxidation reaction. The rate of oxidation decreased with decreasing oxygen partial pressure. Higher partial pressures of oxygen resulted in less oxidation resistance by the ZrB2-SiC-graphite composites.