Oxidative steam reforming of ethanol over PtRu/ZrO2 catalysts modified with sodium and magnesium

被引：17

作者：

Wang, Chi-Han ^{[1
]}

Ho, Kuan-Fu ^{[1
]}

Chiou, Josh Y. Z. ^{[1
]}

Lee, Chin-Ling ^{[1
]}

Yang, Shih-Yi ^{[1
]}

Yeh, Chuin-Tih ^{[2
,3
]}

Wang, Chen-Bin ^{[1
]}

机构：

[1] Natl Def Univ, Dept Chem & Mat Engn, Chung Cheng Inst Technol, Tao Yuan 33509, Taiwan

[2] Yuan Ze Univ Chungli, Dept Chem Engn & Mat Sci, Tao Yuan, Taiwan

[3] Yuan Ze Univ Chungli, Fuel Cell Ctr, Tao Yuan, Taiwan

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 12卷 / 10期

关键词：

Oxidative steam reforming of ethanol; Water gas shift reaction; Hydrogen production; SUPPORTED PLATINUM CATALYSTS; WATER-GAS SHIFT; HYDROGEN-PRODUCTION; H-2; PRODUCTION; NANOPARTICLES; DECOMPOSITION; PERFORMANCE; REFORMATION; RUTHENIUM; PT/ZRO2;

D O I：

10.1016/j.catcom.2011.02.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper reports the catalytic performance of a PtRu/ZrO2 catalyst modified with Na and Mg in an oxidative steam reforming of ethanol (OSRE) reaction tested in the temperature range of 300-400 degrees C. The results show that the PtRuMg1/ZrO2 catalyst requires higher temperatures (T-R-400 degrees C) to achieve complete conversion than either the PtRuNa1/ZrO2 or PtRu/ZrO2 catalysts (T-R-300 degrees C). Also, an apparent coke deposit is found on the PtRuMg1/ZrO2 catalyst. The preferential PtRuNa1/ZrO2 catalyst shows active at temperatures as low as 300 degrees C and produces less CO (< 0.2%) at temperatures lower than 340 degrees C. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：854 / 858

页数：5

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