Effects of VC-LiBOB binary additives on SEI formation in ionic liquid-organic composite electrolyte

被引:14
作者
An, Yongxin [1 ,2 ]
Zuo, Pengjian [1 ]
Du, Chunyu [1 ]
Ma, Yulin [1 ]
Cheng, Xinqun [1 ]
Lin, Jianyi [2 ]
Yin, Geping [1 ]
机构
[1] Harbin Inst Technol, Sch Chem Engn & Technol, State Key Lab Urban Water Resource & Environm, Harbin 150006, Peoples R China
[2] Agcy Sci Technol & Res, Inst Chem & Engn Sci, Singapore, Singapore
关键词
LITHIUM SECONDARY BATTERIES; HYBRID-ELECTRIC VEHICLES; IMPEDANCE; GRAPHITE; CELLS; POWER;
D O I
10.1039/c2ra01040b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A safe electrolyte based on an ionic liquid-organic composite with binary additives was prepared. The stable solid electrolyte interphase (SEI) forms on the surface of a carbon anode by addition of vinylene carbonate (VC) and lithium bis(oxalato) borate (LiBOB) binary additives in ionic liquid-organic electrolyte mixture. The stable SEI effectively prevents the co-intercalation of PP13(+) cations, thus leading to an obvious improvement in the performance of the cell.
引用
收藏
页码:4097 / 4102
页数:6
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