1,3-Double Siloxo-Bridged Zirconium Metallocene for Propene and 1-Hexene Regioselective Oligomerization

被引：13
作者：
Londaitsbehere, Addis [1 ]
Cuenca, Tomas [1 ]
Mosquera, Marta E. G. [1 ]
Cano, Jesus [1 ]
Milione, Stefano [2 ]
Grassi, Alfonso [2 ]
机构：
[1] Univ Alcala de Henares, Dept Quim Inorgan, E-28871 Alcala De Henares, Spain
[2] Univ Salerno, Dept Chim & Biol, I-84084 Salerno, Italy
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 05期
关键词：
ETHYLENE POLYMERIZATION; PROPYLENE POLYMERIZATIONS; POLYPROPYLENE FORMATION; ZIRCONOCENE DICHLORIDE; OLEFIN POLYMERIZATION; MOLECULAR-STRUCTURES; TITANIUM COMPLEXES; ANSA-METALLOCENES; CATALYSTS; DIMERIZATION;
D O I：
10.1021/om2011535
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new 1,3-disiloxo-bridged dichloro zirconocene [{(eta(5)-C5H3)(2)-mu,mu-1,3-(Me2SiOSiMe2)(2)}-ZrCl2] (2) has been synthesized and fully characterized. Complex 2, combined with MAO, polymerizes propene and 1-hexene with high 1,2-regioselectivity, yielding oligomers containing vinylidene end groups produced via a beta-hydrogen elimination reaction.
引用
收藏
页码：2108 / 2111
页数：4
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