Vapor-liquid equilibria in the systems 3-methylpentane plus methyl 1,1-dimethylethyl ether and 3-methylpentane plus methyl 1,1-dimethylpropyl ether at 101.3 kPa

被引：11

作者：

Loras, S ^{[1
]}

Aucejo, A ^{[1
]}

Muñoz, R ^{[1
]}

机构：

[1] Univ Valencia, Fac Quim, Dept Ingn Quim, E-46100 Valencia, Spain

来源：

FLUID PHASE EQUILIBRIA | 1999年 / 156卷 / 1-2期

关键词：

VLE data; activity coefficient; vapor pressure; experimental;

D O I：

10.1016/S0378-3812(99)00028-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Pure-component vapor pressure of 3-methylpentane and vapor-liquid equilibrium (VLE) for the binary systems of 3-methylpentane with methyl 1,1-dimethylethyl ether (MTBE) and with methyl 1,1-dimethylpropyl ether (TAME) at 101.3 kPa have been measured. Both systems exhibit small positive deviations from ideality. They can be described as regular solutions and do not present azeotrope. The activity coefficients and boiling points of the solutions were correlated with its composition by Wilson, UNIQUAC, NRTL, and Wisniak-Tamir equations. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：185 / 195

页数：11

共 15 条

[1]

[Anonymous], 1982, CLASSICAL THERMODYNA

[2] Isobaric vapor-liquid equilibrium in the systems 2-methylpentane plus methyl 1,1-dimethylethyl ether, plus ethyl 1,1-dimethylethyl ether, and plus methyl 1,1-dimethylpropyl ether [J].