Nitrogen Doped Carbon with Metal as Electrocatalysts for the Oxygen Reduction Reaction

被引：12
作者：
Meng, Hui [1 ]
Ouyang, Wenpeng [1 ,2 ]
Xie, Fangyan [3 ]
Zhang, Weihong [3 ]
Chen, Jian [3 ]
Yuan, Dingshen [2 ]
机构：
[1] Jinan Univ, Guangzhou Key Lab Vacuum Coating Technol & New En, Guangdong Prov Key Lab Opt Fiber Sensing & Commun, Siyuan Lab,Dept Phys, Guangzhou 510632, Guangdong, Peoples R China
[2] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
[3] Sun Yat Sen Univ, Instrumental Anal & Res Ctr, Guangzhou 510275, Guangdong, Peoples R China
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2016年 / 163卷 / 13期
基金：
中国国家自然科学基金;
关键词：
MEMBRANE FUEL-CELLS; FE-BASED CATALYSTS; CATHODE CATALYST; ACTIVE-SITES; GRAPHENE; CO; NANOSTRUCTURES; PYROLYSIS; SPECTRA;
D O I：
10.1149/2.0851613jes
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
This work reports nitrogen doped carbon as non-noble metal catalyst for the oxygen reduction reaction (ORR). The carbon material is prepared by the pyrolysis of ion exchange resin. The morphology and ORR activity of the carbon material is influenced by the catalyst used for the graphitization. The effect of acid washing of the pyrolyzed carbon before nitrogen doping is studied. Acid washing is found to be able to remove the impurities/defects of graphitic carbon, which decreases the ORR activity. The nitrogen doped materials show much better ORR activity than undoped one. The ORR activity of the as prepared catalysts is related with metal content and N-O content. (C) 2016 The Electrochemical Society. All rights reserved.
引用
收藏
页码：F1373 / F1379
页数：7
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