Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2}2] for the formation of nickel-containing nanoparticles

被引：20

作者：

Babashkina, Maria G. ^{[1
]}

Safin, Damir A. ^{[1
]}

Garcia, Yann ^{[1
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, MOST Inorgan Chem, B-1348 Louvain, Belgium

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 08期

关键词：

SINGLE-CRYSTAL CHARACTERIZATION; BOND FORMATION; COMPLEX; NI; HYDROTHIOLATION; REDUCTION; EFFICIENT; LIGANDS; CARBON;

D O I：

10.1039/c1dt11755f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Ni{2-PyNHC(S) NP(S)(OiPr)(2)-1,5,7-N, N',S}(2)] ([NiL2I]) dissolved in tri-n-octylphosphine (TOP) is decomposed in hot hexadecylamine (HDA) to give TOP-capped Ni nanoparticles. The same procedure using [Ni{2-MeC6H4NHC(S) NP(S)(OiPr)(2)}(2)-1,3-N, S] ([NiL2II]) and [Ni{PhC(S)NP(S)(OiPr)(2)-1,5-S, S'}(2)] ([NiL2III]) leads to the formation of NiS nanoparticles with the rhombohedral and hexagonal structures, respectively. NiHx nanoparticles were also produced from a mixture of [NiL2I] and N2H4. The obtained Ni nanoparticles can be used for the catalytic addition of Ph2S2 to 1-, 2- and 3-hexynes.

引用

页码：2234 / 2236

页数：3

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