A tetranuclear 3d-4f single molecule magnet:: [CuIILTbIII(hfac)2]2

被引：765
|
作者：
Osa, S
Kido, T
Matsumoto, N
Re, N
Pochaba, A
Mrozinski, J
机构：
[1] Kumamoto Univ, Dept Chem, Fac Sci, Kumamoto 8608555, Japan
[2] Univ G DAnnunzio, Fac Farm, I-66100 Chieti, Italy
[3] Univ Wroclaw, Fac Chem, PL-50382 Wroclaw, Poland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 02期
关键词：
D O I：
10.1021/ja037365e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report now the first single molecule magnet (SMM) consisting of d-f elements. The present study demonstrates that the synthesis of the d-f polynuclear molecule is a very promising approach to SMMs. (1) The d-f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component. Copyright © 2004 American Chemical Society.
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页码：420 / 421
页数：2
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