Synthesis and Structures of a Series of Bulky "Rind-Br" Based on a Rigid Fused-Ring s-Hydrindacene Skeleton

被引：82

作者：

Matsuo, Tsukasa ^{[1
]}

Suzuki, Katsunori ^{[1
]}

Fukawa, Tomohide ^{[1
]}

Li, Baolin ^{[1
]}

Ito, Mikinao ^{[1
]}

Shoji, Yoshiaki ^{[1
]}

Otani, Takashi ^{[1
]}

Li, Liangchun ^{[1
]}

Kobayashi, Megumi ^{[1
]}

Hachiya, Makoto ^{[1
]}

Tahara, Yoshiyuki ^{[1
]}

Hashizume, Daisuke ^{[2
]}

Fukunaga, Takeo ^{[2
]}

Fukazawa, Aiko ^{[3
]}

Li, Yongming ^{[3
]}

Tsuji, Hayato ^{[3
]}

Tamao, Kohei ^{[1
,3
]}

机构：

[1] RIKEN Adv Sci Inst, Funct Elementoorgan Chem Unit, Wako, Saitama 3510198, Japan

[2] RIKEN Adv Sci Inst, Adv Technol Support Div, Wako, Saitama 3510198, Japan

[3] Kyoto Univ, Inst Chem Res, Int Res Ctr Elements Sci IRCELS, Kyoto 6110011, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2011年 / 84卷 / 11期

关键词：

MAIN-GROUP ELEMENTS; SILICON TRIPLE BOND; DISILYNE RSISIR R; MULTIPLE BONDS; ORGANOMETALLIC CHEMISTRY; GROUP-14; ELEMENTS; STABLE COMPOUND; REACTIVITY; DISILENES; GALLIUM;

D O I：

10.1246/bcsj.20110090

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of octa-R-substituted bromo-s-hydrindacenes, "Rind-Br," have been synthesized by a sequence of the Lewis acid catalyzed intramolecular Friedel-Crafts reaction, bromination and vice versa. Their structural features and physical properties depend on the eight R-substituents at the four benzylic positions on the s-hydrindacenyl skeleton. The molecular structures of the Rind-Br have been confirmed by X-ray crystallography, indicating the unique structural diversities of the bulky Rind groups.

引用

页码：1178 / 1191

页数：14

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