One pot synthesis of self-assembled V2O5 nanobelt membrane via capsule-like hydrated precursor as improved cathode for Li-ion battery

被引:35
作者
Wang, Yu [1 ]
Zhang, Hui Juan [2 ]
Siah, Kien Wei [1 ]
Wong, Chee Cheong [2 ]
Lin, Jianyi [1 ]
Borgna, Armando [1 ]
机构
[1] ICES, Singapore 627833, Singapore
[2] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
HIGH-PERFORMANCE; CARBON; NANOPARTICLES; TRANSPARENT; ELECTRODES; STORAGE;
D O I
10.1039/c1jm10783f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel self-assembled V2O5 nanobelt membrane was successfully fabricated for the first time. The synthesis strategy is based on the earlier one-pot formation of V2O5 center dot xH(2)O capsule-like nanobelt membrane via the mediated hydrogen bonding action. The as-made V2O5 nanobelt membrane can be directly integrated into Li-ion batteries serving as a cathode, which exhibit the enhanced electrochemical performance when cycled, including good rate capability, high specific capacity, great cyclability, stability and reliability.
引用
收藏
页码:10336 / 10341
页数:6
相关论文
共 30 条
[1]  
Bai JW, 2010, NAT NANOTECHNOL, V5, P190, DOI [10.1038/NNANO.2010.8, 10.1038/nnano.2010.8]
[2]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[3]   Self-assembled vanadium pentoxide (V2O5) hollow microspheres from nanorods and their application in lithium-ion batteries [J].
Cao, AM ;
Hu, JS ;
Liang, HP ;
Wan, LJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4391-4395
[4]   Fast, completely reversible Li insertion in vanadium pentoxide nanoribbons [J].
Chan, Candace K. ;
Peng, Hailin ;
Twesten, Ray D. ;
Jarausch, Konrad ;
Zhang, Xiao Feng ;
Cui, Yi .
NANO LETTERS, 2007, 7 (02) :490-495
[5]   Positive Electrode Materials for Li-Ion and Li-Batteries [J].
Ellis, Brian L. ;
Lee, Kyu Tae ;
Nazar, Linda F. .
CHEMISTRY OF MATERIALS, 2010, 22 (03) :691-714
[6]   Electrochemical reaction of nanocrystalline Co3O4 thin film with lithium [J].
Fu, ZW ;
Wang, Y ;
Zhang, Y ;
Qin, QZ .
SOLID STATE IONICS, 2004, 170 (1-2) :105-109
[7]   Synthesis and Electrode Performance of Nanostructured V2O5 by Using a Carbon Tube-in-Tube as a Nanoreactor and an Efficient Mixed-Conducting Network [J].
Hu, Yong-Sheng ;
Liu, Xi ;
Mueller, Jens-O. ;
Schloegl, Robert ;
Maier, Joachim ;
Su, Dang Sheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (01) :210-214
[8]   Battery materials for ultrafast charging and discharging [J].
Kang, Byoungwoo ;
Ceder, Gerbrand .
NATURE, 2009, 458 (7235) :190-193
[9]   The study of carbon-coated V2O5 nanoparticles as a potential cathodic material for Li rechargeable batteries [J].
Koltypin, Maxim ;
Pol, Vilas ;
Gedanken, Aharon ;
Aurbach, Doron .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (07) :A605-A613
[10]   Layered Li0.88[Li0.18Co0.33Mn0.49]O2 nanowires for fast and high capacity Li-ion storage material [J].
Lee, Yoojung ;
Kim, Min Gyu ;
Cho, Jaephil .
NANO LETTERS, 2008, 8 (03) :957-961