Enhancement on the CO2 separation performance of mixed matrix membrane using ionic liquid

被引:9
作者
Ahmad, N. N. R. [1 ]
Leo, C. P. [2 ]
Mohammad, A. W. [1 ]
机构
[1] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Dept Chem & Proc Engn, Bangi 43600, Selangor, Malaysia
[2] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Penang, Malaysia
关键词
Thin film; Composite materials; Defects; Interface; COMPOSITE MEMBRANES;
D O I
10.1016/j.matlet.2021.130736
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, two different methods, i.e., ionic liquid (IL)/dope solution blending and post-modification using IL were investigated in asymmetric PSf/SAPO-34 mixed matrix membrane (MMM) modification. The blending of [bmim][BF4] IL with MMM dope solution prior to phase inversion has enhanced the CO2 permeance up to 85.07 GPU but could not elevate the CO2/N2 selectivity since this method was not efficient in defects sealing. However, the defects have successfully been sealed via the post-modification method after phase inversion and resulted in more than 1000% CO2/N2 selectivity improvement over unmodified MMM.
引用
收藏
页数:4
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共 12 条
[1]   Effects of solvent and ionic liquid properties on ionic liquid enhanced polysulfone/SAPO-34 mixed matrix membrane for CO2 removal [J].
Ahmad, N. N. R. ;
Leo, C. P. ;
Ahmad, A. L. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2019, 283 :64-72
[2]   Interfacial sealing and functionalization of polysulfone/SAPO-34 mixed matrix membrane using acetate-based ionic liquid in post-impregnation for CO2 capture [J].
Ahmad, N. N. R. ;
Leo, C. P. ;
Mohammad, A. W. ;
Ahmad, A. L. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2018, 197 :439-448
[3]   Comprehensive Investigation on the Thermal Stability of 66 Ionic Liquids by Thermogravimetric Analysis [J].
Cao, Yuanyuan ;
Mu, Tiancheng .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (20) :8651-8664
[4]   Preparation and characterization of novel Ionic liquid/Pebax membranes for efficient CO2/light gases separation [J].
Estahbanati, Ehsan Ghasemi ;
Omidkh, Mohammadreza ;
Amooghin, Abtin Ebadi .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 51 :77-89
[5]   Gelled Graphene Oxide-Ionic Liquid Composite Membranes with Enriched Ionic Liquid Surfaces for Improved CO2 Separation [J].
Fam, Winny ;
Mansouri, Jaleh ;
Li, Hongyu ;
Hou, Jingwei ;
Chen, Vicki .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (08) :7389-7400
[6]   Investigations with Infrared Spectroscopy on Films of the Ionic Liquid [EMIM]Tf2N [J].
Hoefft, O. ;
Bahr, S. ;
Kempter, V. .
LANGMUIR, 2008, 24 (20) :11562-11566
[7]   Novel mixed matrix membranes based on polymerizable room-temperature ionic liquids and SAPO-34 particles to improve CO2 separation [J].
Hudiono, Yeny C. ;
Carlisle, Trevor K. ;
LaFrate, Andrew L. ;
Gin, Douglas L. ;
Noble, Richard D. .
JOURNAL OF MEMBRANE SCIENCE, 2011, 370 (1-2) :141-148
[8]   Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation [J].
Husain, Shabbir ;
Koros, William J. .
JOURNAL OF MEMBRANE SCIENCE, 2007, 288 (1-2) :195-207
[9]   Pebax-based composite membranes with high gas transport properties enhanced by ionic liquids for CO2 separation [J].
Li, Mengdie ;
Zhang, Xiangping ;
Zeng, Shaojuan ;
Bai, Lu ;
Gao, Hongshuai ;
Deng, Jing ;
Yang, Qingyuan ;
Zhang, Suojiang .
RSC ADVANCES, 2017, 7 (11) :6422-6431
[10]   Nanocomposite membranes consisting of poly(ethylene oxide/Vionic liquid/ZnO for CO2 separation [J].
Rhyu, Seung Yeon ;
Cho, Younghyun ;
Kang, Sang Wook .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2020, 85 (75-80) :75-80