Nanoscale Patterning of Organosilane Molecular Thin Films from the Gas Phase and Its Applications: Fabrication of Multifunctional Surfaces and Large Area Molecular Templates for Site-Selective Material Deposition

被引:23
作者
George, Antony
Knez, Mato [2 ]
Hlawacek, Gregor [1 ]
Hagedoorn, Daniel
Verputten, Hein H. J.
van Gastel, Raoul [1 ]
ten Elshof, Johan E. [1 ]
机构
[1] Univ Twente, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands
[2] Max Planck Inst Microstruct Phys, D-06120 Halle, Saale, Germany
关键词
SELF-ASSEMBLED MONOLAYERS; ATOMIC LAYER DEPOSITION; FUNCTIONAL MATERIALS; LITHOGRAPHY; NANOFABRICATION; RESIST;
D O I
10.1021/la204437r
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple methodology to fabricate micrometer- and nanometer-scale patterned surfaces with multiple chemical functionalities is presented. Patterns with lateral dimensions down to 110 nm were made. The fabrication process involves multistep gas-phase patterning of amine, thiol, alkyl, and fluorinated alkyl-functional organosilane molecules using PDMS molds as shadow masks. Also, a combination process of channel diffused plasma etching of organosilane molecular thin films in combination with masked gas-phase deposition to fabricate multilength scale, multifunctional surfaces is demonstrated.
引用
收藏
页码:3045 / 3052
页数:8
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