On the thermal stability of some ammonium salts

被引：69

作者：

Olszak-Humienik, M ^{[1
]}

机构：

[1] Tech Univ Szczecin, Fac Chem Technol & Chem Engn, PL-71065 Szczecin, Poland

来源：

THERMOCHIMICA ACTA | 2001年 / 378卷 / 1-2期

关键词：

kinetics of decomposition of ammonium salts; eyring parameters; kinetic parameters; ammonium acetate; ammonium nitrate; ammonium chloride;

D O I：

10.1016/S0040-6031(01)00585-8

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal behavior of ammonium acetate, nitrate and chloride were investigated. The dependences between Eyring parameters for particular salts were determined. The dependence of Gibbs free energy of activation on decomposition temperature was calculated. The values of maximum of transformation rate were compared with energies of chemical bonds between ions. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：107 / 112

页数：6

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