Intrinsic triple-emitting 2D copper thiolate coordination polymer as a ratiometric thermometer working over 400 K range

被引：36

作者：

Veselska, Oleksandra ^{[1
]}

Podbevsek, Darjan ^{[2
]}

Ledoux, Gilles ^{[2
]}

Fateeva, Alexandra ^{[3
]}

Demessence, Aude ^{[1
]}

机构：

[1] Univ Claude Bernard Lyon 1, Inst Rech Catalyse & Environm Lyon IRCELYON, UMR CNRS 5256, Villeurbanne, France

[2] Univ Claude Bernard Lyon 1, ILM, UMR CNRS 5306, Villeurbanne, France

[3] Univ Claude Bernard Lyon 1, LMI, UMR CNRS 5615, Villeurbanne, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 90期

关键词：

DUAL-EMISSION; THERMOCHROMIC-LUMINESCENCE; ORGANIC FRAMEWORKS; CHARGE MOBILITY; IODIDE CLUSTERS; CU NANOCLUSTERS; COMPLEXES; LIGHT; TEMPERATURE; LIGANDS;

D O I：

10.1039/c7cc06815h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A copper thiolate coordination polymer, [Cu(p-SPhCO2Me)](n), is described and exhibits, under UV, luminescence thermochromism, associated to a unique well-separated triple emission. This compound is the most promising candidate as a ratiometric temperature sensor, working in a wide temperature range, from 100 to 500 K, with a great sensitivity.

引用

页码：12225 / 12228

页数：4

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