Growth and characterization of 2-Methylimidazolium D-tartrate single crystal

被引：19

作者：

Srinivasan, T. P. ^{[1
,2
]}

Anandhi, S. ^{[1
]}

Gopalakrishnan, R. ^{[1
]}

机构：

[1] Anna Univ, Dept Phys, Crystal Res Lab, Madras 600025, Tamil Nadu, India

[2] KLN Coll Engn, Dept Phys, Pottapalayam 630611, Sivagangai, India

来源：

JOURNAL OF CRYSTAL GROWTH | 2011年 / 318卷 / 01期

关键词：

X-ray diffraction; Growth from solutions; Nonlinear optical materials; Dielectric properties; NONLINEAR-OPTICAL-MATERIALS; FILMS; PURE; ACID;

D O I：

10.1016/j.jcrysgro.2010.11.021

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Single crystal of 2-Methylimidazolium D-tartrate (2MImdT; C8N2O6H12) has been grown by slow evaporation solution growth technique at room temperature using mixed solvents of ethanol and deionized water. Single crystal X-ray diffraction study confirms that 2-Methylimidazolium D-tartrate belongs to monoclinic crystal system with non-centrosymmetric space group P2(1). The Fourier transform infrared spectrum of 2-Methylimidazolium D-tartrate reveals the presence of methyl and carboxyl functional groups in the compound. The mechanical properties of 2MImdT crystal were studied. The theoretical factor group analysis predicts 168 optical modes in the title compound. The dielectric behavior of 2MImdT crystals was studied at different frequencies and temperatures. Decomposition and melting point of 2MImdT were found using thermal measurements. SHG behavior of the title compound was demonstrated using Q-switched Nd:YAG laser. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：768 / 773

页数：6

共 22 条

[1] ORGANIC SALTS OF L-TARTARIC ACID - MATERIALS FOR 2ND HARMONIC-GENERATION WITH A CRYSTAL-STRUCTURE GOVERNED BY AN ANIONIC HYDROGEN-BONDED NETWORK [J].

AAKEROY, CB ;

HITCHCOCK, PB ;

SEDDON, KR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) :553-555

[2]

[Anonymous], 1956, Mikroskopie

[3]

Benet C.J., 1994, CRYST RES TECHNOL, V29, P707

[4] DISTORTION-INDUCED INTENSITY OF RAMAN MODES OF MOLECULAR UNITS IN DIFFERENT CRYSTAL ORIENTATIONS [J].

BHATTACHARJEE, R .

JOURNAL OF RAMAN SPECTROSCOPY, 1990, 21 (08) :491-494

[5]

CAHOON JR, 1971, METALL TRANS, V2, P1979

[6] Structural and optical characterization of ZnO nanocrystalline films deposited by sputtering [J].

Chawla, Amit Kumar ;

Kaur, Davinder ;

Chandra, Ramesh .

OPTICAL MATERIALS, 2007, 29 (08) :995-998

[7] NONLINEAR OPTICAL-MATERIALS [J].

EATON, DF .

SCIENCE, 1991, 253 (5017) :281-287

[8] INCORPORATION OF IMIDAZOLIUM CATIONS INTO AN ENANTIOMERIC TARTRATE HOST LATTICE - DESIGNING NEW NONLINEAR-OPTICAL MATERIALS [J].

FULLER, J ;

CARLIN, RT ;

SIMPSON, LJ ;

FURTAK, TE .

CHEMISTRY OF MATERIALS, 1995, 7 (05) :909-919

[9] Electrical conductivity studies on pure and copper added strontium tartrate trihydrate crystals [J].

Gowri, B ;

Shajan, XS .

MATERIALS LETTERS, 2006, 60 (11) :1338-1340

[10] Crystal and Molecular Structure Analysis of 2-Methylimidazole [J].

Hachula, Barbara ;

Nowak, Maria ;

Kusz, Joachim .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (03) :201-206

← 1 2 3 →