Synthesis and Magnetic Properties of a Series of Octanuclear [Fe6Ln2] Nanoclusters

被引：65
作者：
Han, Song-De [1 ,2 ]
Liu, Sui-Jun [1 ,2 ,3 ]
Wang, Qing-Lun [1 ,2 ]
Miao, Xiao-Hong [1 ,2 ]
Hu, Tong-Liang [1 ,2 ]
Bu, Xian-He [1 ,2 ]
机构：
[1] Nankai Univ, Dept Chem, TKL Met & Mol Based Mat Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[3] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 05期
关键词：
SINGLE-MOLECULE-MAGNET; POLYNUCLEAR IRON CHEMISTRY; SITU LIGAND CONVERSION; COORDINATION POLYMERS; STRUCTURAL TYPES; COBALT-PIVALATE; CLUSTERS; COMPLEXES; RELAXATION; CAGE;
D O I：
10.1021/acs.cgd.5b00024
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of polydentate ligand Bis-tris propane {(CH2OH)(3)CNH-(CH2)(3)NHC(CH2OH)(3)} with Ln(NO3)(3)-6H(2)O and Fe3O precursor resulted in the formation of a series of Fe(6)Ln(2) nanoclusters. Magnetic measurements indicate that the Fe-6 core exhibits ferrimagnetic behavior, and slow magnetic relaxation was observed in Fe6Dy2 and Fe6Tb2.
引用
收藏
页码：2253 / 2259
页数：7
相关论文
共 76 条
[1]   A Co36 Cluster Assembled from the Reaction of Cobalt Pivalate with 2,3-Dicarboxypyrazine [J].
Albores, Pablo ;
Rentschler, Eva .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (49) :9366-9370
[2]   Structural and magnetic characterization of a 1D chain of [Co(II)2(μ-aqua)(μ-carboxylate)2] strung cores [J].
Albores, Pablo ;
Rentschler, Eva .
DALTON TRANSACTIONS, 2009, (14) :2609-2615
[3]  
[Anonymous], 1998, RIG PROC AUT
[4]   Synthesis and crystal structures of the ligand-stabilized over chalcogenide clusters [Ag154Se77(dppxy)18], [Ag320(StBu)60S130(dppp)12], [Ag352S128(StC5H11)96], and [Ag490S188(StC5H11)114] [J].
Anson, Christopher E. ;
Eichhofer, Andreas ;
Issac, Ibrahim ;
Fenske, Dieter ;
Fuhr, Olaf ;
Sevillano, Paloma ;
Persau, Claudia ;
Stalke, Dietmar ;
Zhang, Jiatao .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (07) :1326-1331
[5]   Synthetic and structural studies of cobalt-pivalate complexes [J].
Aromí, G ;
Batsanov, AS ;
Christian, P ;
Helliwell, M ;
Parkin, A ;
Parsons, S ;
Smith, AA ;
Timco, GA ;
Winpenny, REP .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (20) :5142-5161
[6]   Design of magnetic coordination complexes for quantum computing [J].
Aromi, Guillem ;
Aguila, David ;
Gamez, Patrick ;
Luis, Fernando ;
Roubeau, Olivier .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (02) :537-546
[7]   Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a 'rabbit-face' topology and a discrete Ni18 'molecular chain' [J].
Athanasopoulou, Angeliki A. ;
Pilkington, Melanie ;
Raptopoulou, Catherine P. ;
Escuer, Albert ;
Stamatatos, Theocharis C. .
CHEMICAL COMMUNICATIONS, 2014, 50 (95) :14942-14945
[8]   Unusual structural types in polynuclear iron chemistry from the use of N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine (edteH4):: Fe5, Fe6, and Fe12 clusters [J].
Bagai, Rashmi ;
Daniels, Matthew R. ;
Abboud, Khalil A. ;
Christou, George .
INORGANIC CHEMISTRY, 2008, 47 (08) :3318-3327
[9]   A new N,N,O chelate for transition metal chemistry:: Fe5 and Fe6 clusters from the use of 6-hydroxymethyl-2,2′-bipyridine (hmbpH) [J].
Bagai, Rashmi ;
Abboud, Khalil A. ;
Christou, George .
INORGANIC CHEMISTRY, 2007, 46 (14) :5567-5575
[10]   Diversity of new structural types in polynuclear iron chemistry with a tridentate N,N,O ligand [J].
Bagai, Rashmi ;
Datta, Saiti ;
Betancur-Rodriguez, Amalia ;
Abboud, Khalil A. ;
Hill, Stephen ;
Christou, George .
INORGANIC CHEMISTRY, 2007, 46 (11) :4535-4547
12345678