Ru(II) Phenanthroline Complex As Catalyst for Chemoselective Hydrogenation of Nitro-Aryls in a Green Process

被引：24

作者：

Deshmukh, Amit A. ^{[1
,3
]}

Prashar, Atul K. ^{[1
]}

Kinage, Anil K. ^{[1
]}

Kumar, Rajiv ^{[2
]}

Meijboom, Reinout ^{[3
]}

机构：

[1] Natl Chem Lab, Pune 411008, Maharashtra, India

[2] Tata Chem Ltd, Pune, Maharashtra, India

[3] Univ Johannesburg, Dept Chem, Ctr Synth & Catalysis, ZA-2006 Johannesburg, South Africa

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2010年 / 49卷 / 23期

关键词：

SUPERCRITICAL CARBON-DIOXIDE; SUPPORTED PLATINUM CATALYST; SELECTIVE HYDROGENATION; NITROBENZENE HYDROGENATION; SUBSTITUTED NITROAROMATICS; RUTHENIUM(II) COMPLEXES; MOLECULAR-INTERACTIONS; O-CHLORONITROBENZENE; REACTION-KINETICS; CHLOROANILINE;

D O I：

10.1021/ie1015969

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Ru(II) Phenanthroline [Ru(II)(Phen)(n) where n = 1,2,3] complexes were used as highly chemoselective catalysts for hydrogenation of nitro aryls using molecular hydrogen in an aqueous media. Water, universal solvent, was used as a reaction mixture for hydrogenation of nitro-aryls to make the process green. The chemoselectivity in hydrogenation of substituted nitrobenzene to substituted aniline was obtained as high as >99% at about complete conversion of substituted nitrobenzene. The parametric effects, including effect of solvent, effect of ligand, effect of metal to ligand ratio, effect of temperature and pressure, were studied in detail to obtain the best results. The Ru(Phen)(n) was characterized by FTIR, UV-vis, and XPS.

引用

页码：12180 / 12184

页数：5

共 35 条

[1] PYRIDINE AND 2,2'-BIPYRIDYL DERIVATIVES OF NITRATOPENTACARBONYLMANGANESE(1) [J].

ADDISON, CC ;

KILNER, M .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (09) :1249-&

[2]

[Anonymous], 2001, STUD SURF SCI CAT

[3]

Arounaguiri S, 2000, P INDIAN AS-CHEM SCI, V112, P1

[4]

BACHAMP A, 1854, ANN CHIM PARIS, V42, P186

[5] A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO2 catalysts:: A cooperative effect between gold and the support [J].

Boronat, Merce ;

Concepcion, Patricia ;

Corma, Avelino ;

Gonzalez, Silvia ;

Illas, Francesc ;

Serna, Pedro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :16230-16237

[6] A different reaction pathway for the reduction of aromatic nitro compounds on gold catalysts [J].

Corma, Avelino ;

Concepcion, Patricia ;

Serna, Pedro .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7266-7269

[7] Highly chemoselective catalytic system for hydrogenation of diketones to ketols: An environmentally benevolent system [J].

Deshmukh, Amit A. ;

Kinage, Anil K. ;

Kumar, Rajiv .

CATALYSIS LETTERS, 2008, 120 (3-4) :257-260

[8] Chemoselective hydrogenation of substituted nitroaromatics using novel water-soluble iron complex catalysts [J].

Deshpande, RM ;

Mahajan, AN ;

Diwakar, MM ;

Ozarde, PS ;

Chaudhari, RV .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (14) :4835-4838

[9] Hydrogenation and hydrogenolysis of nitro-, nitroso-, azo-, azoxy- and other nitrogen-containing compounds on palladium [J].

Figueras, F ;

Coq, B .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) :223-230

[10]

Höller V, 2000, CHEM ENG TECHNOL, V23, P251

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