Fullerene anions: Jahn-Teller or pseudo-Jahn-Teller effects?

被引：11
|
作者：
Borshch, SA
Prassides, K
机构：
[1] ECOLE NORMALE SUPER LYON,CHIM THEOR LAB,F-69364 LYON 07,FRANCE
[2] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 22期
关键词：
D O I：
10.1021/jp960015c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The vibronic problems appearing in manifolds of the electronic terms of C-60 anions are studied. It is shown that the vibronic coupling of the T-1u molecular orbital with the h(g) vibrations induces pseudo-Jahn-Teller and Jahn-Teller couplings within the electronic terms. The resulting vibronic distortions are determined by the interplay of interelectronic and vibronic interactions. In certain cases the vibronic interaction of excited electronic terms can change the spin multiplicity of the ground state.
引用
收藏
页码：9348 / 9351
页数：4
相关论文
共 50 条
  • [1] Fullerene anions: Jahn-Teller or pseudo-Jahn-Teller effects?
    CNRS, Villeurbanne, France
    J Phys Chem, 22 (9348-9351):
  • [2] ON JAHN-TELLER AND PSEUDO-JAHN-TELLER EFFECT
    ALPER, JS
    SILBEY, R
    JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (07): : 3129 - &
  • [3] Photophysics of barrelene: The Jahn-Teller and pseudo-Jahn-Teller effects
    Ghanta, Susanta
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1110 : 32 - 43
  • [4] Jahn-Teller and pseudo-Jahn-Teller effects in trifluoromethane radical cation
    Ghanta, Susanta
    JOURNAL OF MOLECULAR STRUCTURE, 2016, 1118 : 293 - 300
  • [5] The Jahn-Teller and pseudo-Jahn-Teller effects in the propyne radical cation
    Kanakati, Arun Kumar
    Rani, Vadala Jhansi
    Mahapatra, S.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (27) : 16522 - 16537
  • [6] The Jahn-Teller and pseudo-Jahn-Teller effects in the photoelectron spectrum of cyclopropane
    Venkatesan, T. S.
    Mahapatra, S.
    Koeppel, H.
    Cederbaum, L. S.
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 838 (1-3) : 100 - 106
  • [7] MULTIMODE JAHN-TELLER AND PSEUDO-JAHN-TELLER EFFECTS IN BF3+
    HALLER, E
    KOPPEL, H
    CEDERBAUM, LS
    VONNIESSEN, W
    BIERI, G
    JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (03): : 1359 - 1370
  • [8] Orientational polarizability of solids induced by the Jahn-Teller and pseudo-Jahn-Teller effects
    Polinger, Victor
    Bersuker, Isaac B.
    PHYSICAL REVIEW B, 2024, 109 (22)
  • [9] Relativistic multimode Jahn-Teller and pseudo-Jahn-Teller effects in tetrahedral systems
    Volokhov, V. M.
    Poluyanov, L. V.
    CHEMICAL PHYSICS LETTERS, 2023, 811
  • [10] Combined Jahn-Teller and Pseudo-Jahn-Teller effects in the benzene radical cation
    Köppel, H
    Bâldea, I
    Szalay, PG
    ADVANCES IN QUANTUM CHEMISTRY, VOL 44: MANIFESTATIONS OF VIBRONIC COUPLING IN CHEMISTRY AND PHYSICS, 2003, 44 : 199 - 217
12345