Synthesis and crystal structure of (Bu4N)2Hg(i-mnt)2

被引：0

作者：

Zheng, HG

Jin, QH

Xin, XQ

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2001年 / 12卷 / 02期

关键词：

synthesis; crystal structure; mercury(II) complex; isomaleonitrile dithiolate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and the crystal structure of the title compound (Bu4N)(2)Hg(S2C=C(CN)(2))(2) 1 is reported herein. The crystal is attributed to trielinic system and space group P-1, fw=965.88. The crystal lattice parameters are a=9.45(1), b=15.827(2), c=17.619(2)Angstrom, alpha =108.12(2), beta =99.54(2), gamma =97.60(2)degrees, V=2421.9(8)Angstrom, mu (MoKalpha)=3.390mm(-1), Z=2, D-c=1.324g.cm(-3), F(000)=996, R=0.054, wR=0.058.

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页码：185 / 186

页数：2

相关论文

共 10 条

[1] METAL-COMPLEXES AS LIGANDS .4. STRUCTURES OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,2-DICYANO-1,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C2(CN)2)2, AND OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,1-DICYANO-2,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C=C(CN)2)2 [J].

COUCOUVANIS, D ;

BAENZIGER, NC ;

JOHNSON, SM .

INORGANIC CHEMISTRY, 1974, 13 (05) :1191-1199

[2]

GHOSH R, 1996, CHEM COMMUN, P435

[3] CHEMISTRY OF SUBVALENT MAIN GROUP-METALS WITH DITHIOLATES .2. X-RAY STRUCTURAL, THERMAL, AND THEORETICAL INVESTIGATIONS ON THE NOVEL ONE-DIMENSIONAL STACKING STRUCTURE K2[PB(S2C=C(CN)2)2].2H2O [J].

HUMMEL, HU ;

MESKE, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :627-630

[4] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF TETRAETHYLAMMONIUM BIS[1,1-DICYANOETHYLENE-2,2-DITHIOLATO]PLATINATE(II) [J].

HUMMEL, HU .

TRANSITION METAL CHEMISTRY, 1987, 12 (02) :172-174

[5] THE STRUCTURE OF MU-(1,1-DICYANOETHYLENE-2,2-DITHIOLATO-S,S')-BIS(TRIPHENYLPHOSPHINE)DIGOLD(I) DIETHYL-ETHER SOLVATE [J].

KHAN, MNI ;

WANG, S ;

HEINRICH, DD ;

FACKLER, JP .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :822-825

[6] A NOVEL SQUARE-PLANAR CD(II) WITH 4 SULFUR DONOR LIGANDS - CRYSTAL-STRUCTURE AND CD-113 NMR [J].

LI, HY ;

AMMA, EL .

INORGANICA CHIMICA ACTA, 1990, 177 (01) :5-7

[7] Crystallographic evidence for the coordination performance of WO2S22- synthesis, characterization and crystal structure of palladium complexes with mixed-ligand thiotungstates and 1,2-dithiolates:: [NBu4]2[PdWO2S2(C3S5)] and [NBu4][PdWS4(C4N2S2)] [J].

Long, DL ;

Chen, JT ;

Huang, JS .

INORGANICA CHIMICA ACTA, 1999, 285 (02) :241-248

[8]

Long DL, 1995, CHINESE CHEM LETT, V6, P899

[9] Syntheses and crystal structures of isomalononitrile dithiolato complexes (Bu(4)N)(2)Zn(i-mnt)(2) and (Et(4)N)(2)Pd(i-mnt)(2) [J].

Long, DL ;

Hou, HW ;

Xin, XQ ;

Yu, KB ;

Luo, BS ;

Chen, LR .

JOURNAL OF COORDINATION CHEMISTRY, 1996, 38 (1-2) :15-24

[10] SYNTHESIS AND OPTICAL LIMITING CAPABILITY OF CUBANE-LIKE MIXED-METAL CLUSTERS (N-BU(4)N)(3)[MOAG(3)BRX(3)S(4)] (X=CL AND I) [J].

SHI, S ;

JI, W ;

TANG, SH ;

LANG, JP ;

XIN, XQ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3615-3616