Thermal degradation and flame retardancy of polypropylene/C60 nanocomposites

被引:70
作者
Fang, Zhengping [1 ,2 ]
Song, Pingan [1 ,2 ]
Tong, Lifang [2 ]
Guo, Zhenghong [1 ]
机构
[1] Zhejiang Univ, Ningbo Inst Technol, Lab Polymer Mat & Engn, Ningbo 315100, Zhejiang, Peoples R China
[2] Zhejiang Univ, Minist Educ, Key Lab Macromol Synth & Functionalizat, Inst Polymer Composites, Hangzhou 310027, Peoples R China
关键词
fullerene; polypropylene; thermal stability; flame retardancy;
D O I
10.1016/j.tca.2008.04.019
中图分类号
O414.1 [热力学];
学科分类号
摘要
Nanocomposites based on polypropylene (PP) and fullerene C-60 (in the range of 0.5-2 wt%) were prepared by melt compounding. It was observed that C-60 Could not only significantly enhance the thermal stability in nitrogen but also considerably delay the oxidation decomposition in air of polypropylene. Unexpectedly, the incorporation of C-60 greatly reduced the heat release rate of PP and resulted in a longer time to ignition. And the free radicals-trapping mechanism of C-60 was proposed for explaining the enhanced thermal properties and improved flame retardancy of PR Therefore, C-60 will be an effective flame retardant like carbon nanotubes and clay for PR (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:106 / 108
页数:3
相关论文
共 10 条
[1]  
Kashiwagi T, 2002, MACROMOL RAPID COMM, V23, P761, DOI 10.1002/1521-3927(20020901)23:13<761::AID-MARC761>3.0.CO
[2]  
2-K
[3]   Nanoparticle networks reduce the flammability of polymer nanocomposites [J].
Kashiwagi, T ;
Du, FM ;
Douglas, JF ;
Winey, KI ;
Harris, RH ;
Shields, JR .
NATURE MATERIALS, 2005, 4 (12) :928-933
[4]   Thermal and flammability properties of polypropylene/carbon nanotube nanocomposites [J].
Kashiwagi, T ;
Grulke, E ;
Hilding, J ;
Groth, K ;
Harris, R ;
Butler, K ;
Shields, J ;
Kharchenko, S ;
Douglas, J .
POLYMER, 2004, 45 (12) :4227-4239
[5]   THE INFRARED AND ULTRAVIOLET-ABSORPTION SPECTRA OF LABORATORY-PRODUCED CARBON DUST - EVIDENCE FOR THE PRESENCE OF THE C-60 MOLECULE [J].
KRATSCHMER, W ;
FOSTIROPOULOS, K ;
HUFFMAN, DR .
CHEMICAL PHYSICS LETTERS, 1990, 170 (2-3) :167-170
[6]   RADICAL REACTIONS OF C60 [J].
KRUSIC, PJ ;
WASSERMAN, E ;
KEIZER, PN ;
MORTON, JR ;
PRESTON, KF .
SCIENCE, 1991, 254 (5035) :1183-1185
[7]  
Zanetti M, 2001, MACROMOL RAPID COMM, V22, P176, DOI 10.1002/1521-3927(200102)22:3<176::AID-MARC176>3.0.CO
[8]  
2-C
[9]  
ZHANG J, 2005, POLYM COMBUSTION FLA, P32
[10]   Studies on the mechanism by which the formation of nanocomposites enhances thermal stability [J].
Zhu, J ;
Uhl, FM ;
Morgan, AB ;
Wilkie, CA .
CHEMISTRY OF MATERIALS, 2001, 13 (12) :4649-4654