Fabrication of Direct Z-scheme α-Fe2O3/FeVO4 Nanobelts with Enhanced Photoelectrochemical Performance

被引:20
作者
Wang, Qinyu [1 ]
Liu, Zhendong [1 ]
Lu, Qifang [1 ]
Guo, Enyan [1 ]
Wei, Mingzhi [1 ]
机构
[1] Qilu Univ Technol, Shandong Acad Sci, Sch Mat Sci & Engn, Shandong Prov Key Lab Proc & Testing Technol Glas, Jinan 250353, Shandong, Peoples R China
关键词
alpha-Fe2O3/FeVO4; Electrospinning; nanobelts; Photocatalyst; Z-scheme; PHOTOCATALYTIC ACTIVITY; OPTICAL-PROPERTIES; CU3V2O8; NANOPARTICLES; BIVO4; NANOFIBERS; FACILE SYNTHESIS; FEVO4; NANORODS; DEGRADATION; NANOSTRUCTURES; HETEROJUNCTION; NANOCOMPOSITES;
D O I
10.1002/slct.201702654
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A direct Z-scheme type alpha-Fe2O3/FeVO4 heterostructured photocatalyst with novel nanobelt structure just like the leaves of bryophyllum pinnatum has been successfully synthesized for the first time via integrating a facile electrospinning with annealing procedure. The as-prepared products are characterized by XRD, FT-IR, XPS, SEM, TEM, HRTEM, BET, PL, TOC, HPLC, EIS, Micro-Raman and UV-vis absorbance spectroscopy.The photocatalytic activity of alpha-Fe2O3/FeVO4 nanobelts evaluated by themethylene blue (MB) degradation under visible light irradiation could be ascribed to the extended light absorption and improved charge separation efficiency. A reasonable Z-scheme photocatalytic mechanism is proposed on the basis of structural and electrochemical characterization, which could well explain the enhanced migration rate of photogenerated carriers in alpha-Fe2O3/FeVO4 heterojunctions.
引用
收藏
页码:809 / 815
页数:7
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