Photonic Control of Surface Anchoring on Solid Colloids Dispersed in Liquid Crystals

The anchoring of liquid-crystal (LC) mesogens to the surfaces of colloids is an important factor in determining intercolloidal interactions and the symmetry of the ensuing colloidal assembly in nematic colloids. The dynamic control of surface anchoring could therefore provide a handle to tune the colloidal organization and resulting properties in these systems. In this article, we report our results on the study of thermotropic nematic LC (E7) dispersions of silica and glass microcolloids bearing photosensitive surface azobenzene groups. By the photoinduced modulation of the colloidal-LC interfacial properties, due to the trans-cis isomerization of azobenzene units, we tune the anchoring on silica colloids from homeotropic (trans-azobenzene) to homogeneous planar (cis-azobenzene) reversibly. In tune with the change in surface anchoring, the interparticle interactions were also dictated by dipolar and quadrupolar symmetries for homeotropic and homogeneous planar anchoring, respectively. In our experiments, we find that, in addition to the isomerization state of the surface-bound azobenzene units, the nature of the colloid plays a crucial role in determining the anchoring state obtained on applying photostimuli. We also study the LC anchoring on colloids as a function of the azobenzene surface density and find that beyond a threshold value the anchoring properties remain invariant.