Electrode material of core-shell hybrid MoS2@C/CNTs with carbon intercalated few-layer MoS2 nanosheets

被引:43
作者
Guan, Xunbao [1 ]
Zhao, Liping [1 ]
Zhang, Peng [1 ]
Liu, Jing [1 ]
Song, Xuefeng [1 ]
Gao, Lian [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Metall Matrix Composite Mat, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
Intercalated few-layer MoS2; Coaxial nanocable; Supercapacitor electrode; Electrochemical; Cyclic stability; REDUCED GRAPHENE OXIDE; MOLYBDENUM-DISULFIDE; IONIC LIQUID; CNT BACKBONE; SOLID-STATE; BINDER-FREE; PERFORMANCE; SUPERCAPACITOR; COMPOSITE; NANOSTRUCTURE;
D O I
10.1016/j.mtener.2019.100379
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
MoS2@C/CNTs is synthesized and applied as electrode of supercapacitors. Few-layer MoS2 nanosheets, with amorphous carbon located at both the surface and interlayers, grow on the CNTs surface and form coaxial nanocable structure MoS2@C/CNTs. The intercalated amorphous carbon broadens interlayer spacing of MoS2 (002) planes, which provides both electron and ions transmission path as well as protection to volume change of MoS2 during electrochemical processes. The MoS2@C/CNTs electrode exhibits excellent electrochemical properties, such as high specific capacitance and excellent cyclic stability. The specific capacitance is 335 F/g at current density of 1 A/g and capacitance retention ratio of 127% is achieved after 40000 cycles. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页数:9
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