Photochemical reactions of linear alkane radical cations in low-temperature matrices

被引：4
|
作者：
Tyurin, DA [1 ]
Mel'nikov, MY [1 ]
Belevskii, VN [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119899, Russia
来源：
HIGH ENERGY CHEMISTRY | 2001年 / 35卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1023/A:1017632511277
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The radical cations of linear alkanes (n-pentane, n-heptane) trapped in various matrices (Freon-11, Freon-113, Freon-113a, mixture of Freon-11 and Freon-114B2, and sulfur hexafluoride) were found to undergo the following types of photochemical reactions: (1) charge transfer to the matrix followed by neutralization, (2) isomerization and unimolecular decomposition, and (3) deprotonation. The absorption spectra of the radical cations were characterized, and the quantum yields of reactions occurring in different matrices at 77 K were determined. It was shown that the reaction pathway and efficiency of the photochemical processes observed for a given radical cation in different matrices with similar physical and chemical characteristics could considerably differ.
引用
收藏
页码：236 / 246
页数：11
相关论文
共 50 条
  • [1] Photochemical Reactions of Linear Alkane Radical Cations in Low-Temperature Matrices
    D. A. Tyurin
    M. Ya. Mel'nikov
    V. N. Belevskii
    High Energy Chemistry, 2001, 35 : 236 - 246
  • [2] Photochemistry of ethylbenzene radical cations in low-temperature freonic matrices
    Mel'nikov, MY
    Marushkevich, KI
    Baranova, IA
    Mel'nikova, PL
    Tyurin, DA
    HIGH ENERGY CHEMISTRY, 2003, 37 (02) : 96 - 100
  • [3] Photochemistry of Ethylbenzene Radical Cations in Low-Temperature Freonic Matrices
    M. Ya. Mel'nikov
    K. I. Marushkevich
    I. A. Baranova
    O. L. Mel'nikova
    D. A. Tyurin
    High Energy Chemistry, 2003, 37 : 96 - 100
  • [4] ELECTRON-SPIN RESONANCE STUDIES OF STRUCTURES AND REACTIONS OF RADICAL CATIONS OF A SERIES OF CYCLOALKANES IN LOW-TEMPERATURE MATRICES
    IWASAKI, M
    TORIYAMA, K
    NUNOME, K
    FARADAY DISCUSSIONS, 1984, 78 : 19 - 33
  • [5] Photoinduced Transformations in Low-Temperature Matrices Containing Radical Cations of Organotin Compounds
    E. A. Belokon’
    V. I. Pergushov
    D. A. Tyurin
    M. P. Egorov
    M. Ya. Mel’nikov
    High Energy Chemistry, 2005, 39 : 224 - 231
  • [6] Photoinduced transformations in low-temperature matrices containing radical cations of organotin compounds
    Belokon, EA
    Pergushov, VI
    Tyurin, DA
    Egorov, MP
    Mel'nikov, MY
    HIGH ENERGY CHEMISTRY, 2005, 39 (04) : 224 - 231
  • [7] Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices
    Sorokin, Ivan D.
    Gromov, Oleg I.
    Pergushov, Vladimir I.
    Pomogailo, Dania A.
    Melnikov, Mikhail Ya.
    MENDELEEV COMMUNICATIONS, 2020, 30 (01) : 67 - 69
  • [8] Photochemical reactions of radical cations of dimethylformamide in freon matrices at 77 K
    M. Ya. Mel'nikov
    V. N. Belevskii
    S. I. Belopushkin
    O. L. Mel'nikova
    Russian Chemical Bulletin, 1997, 46 : 1245 - 1247
  • [9] Photochemical reactions of radical cations of dimethylformamide in freon matrices at 77 K
    Melnikov, MY
    Belevskii, VN
    Belopushkin, SI
    Melnikova, OL
    RUSSIAN CHEMICAL BULLETIN, 1997, 46 (07) : 1245 - 1247
  • [10] EPR study of methyl and ethyl acrylate radical cations and their transformations in low-temperature matrices
    Knolle, W
    Feldman, VI
    Janovsky, I
    Naumov, S
    Mehnert, R
    Langguth, H
    Sukhov, FF
    Orlov, AY
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (03): : 687 - 699
12345