Conditions for Minimizing Direct Reduction in Smelting Reduction Iron Making

被引:4
作者
Shim, Yang-Sub [1 ]
Jung, Sung-Mo [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Grad Inst Ferrous Technol, Pohang 37673, South Korea
关键词
smelting reduction; direct reduction; FINEX; COREX; reduction rate; reactivity of char; CARBON-MONOXIDE MIXTURES; GASIFICATION REACTIVITY; COAL; BEHAVIOR; MECHANISM; HEMATITE; HYDROGEN; STICKING; ORE;
D O I
10.2355/isijinternational.ISIJINT-2017-479
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In a 2 stage-smelting reduction process, it is favorable to lower the reduction degree of iron ore in a pre-reducing unit by lowering its temperature to avoid any troubles due to stickiness of high reduced iron ore. However, less pre-reduced iron ore can induce direct reduction in a melter-gasifier, which can increase coal ratio. In this case, the direct reduction ratio is determined by the reducibility of Pre-Reduced Iron ore (PRI) and the reactivity of coal with CO2. PRI was made into pellets and its reducibility was measured in various temperatures and H-2 contents. Coal was carbonized in melter-gasifier condition and then its reactivity with CO2 was measured in various temperatures and CO2 contents. The possibility that direct reduction takes place in a melter-gasifier was high because the PRI pellet was reduced more slowly than unreduced iron ore and the char reacted more actively than coke. The direct reduction rate in a meltergasifier was roughly drawn as the product of the CO2 content in the ascending gas and the reaction rate constant of coal with CO2 and the way to minimize the direct reduction ratio was discussed with that diagram.
引用
收藏
页码:274 / 281
页数:8
相关论文
共 16 条
[1]  
Biswas A. K., 1981, PRINCIPLES BLAST FUR, P77
[2]  
Biswas A. K., 1981, PRINCIPLES BLAST FUR, P42
[3]   Kinetic analysis of the iron oxide reduction using hydrogen-carbon monoxide mixtures as reducing agent [J].
Bonalde, A ;
Henriquez, A ;
Manrique, M .
ISIJ INTERNATIONAL, 2005, 45 (09) :1255-1260
[4]   Alternative emerging ironmaking technologies for energy-efficiency and carbon dioxide emissions reduction: A technical review [J].
Hasanbeigi, Ali ;
Arens, Marlene ;
Price, Lynn .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2014, 33 :645-658
[5]   Effects of metal catalysts on CO2 gasification reactivity of biomass char [J].
Huang, Yanqin ;
Yin, Xiuli ;
Wu, Chuangzhi ;
Wang, Congwei ;
Xie, Jianjun ;
Zhou, Zhaoqiu ;
Ma, Longlong ;
Li, Haibin .
BIOTECHNOLOGY ADVANCES, 2009, 27 (05) :568-572
[6]  
Kim S. M., 2016, POSCO RES REP, V2, P10
[7]  
Kim S. M., 2015, POSCO RES REP, V1, P59
[8]   High-Temperature Gasification Reactivity with Steam of Coal Chars Derived under Various Pyrolysis Conditions in a Fluidized Bed [J].
Liu, Hao ;
Zhu, He ;
Kaneko, Mashhiro ;
Kato, Shigeru ;
Kojima, Toshinori .
ENERGY & FUELS, 2010, 24 (01) :68-75
[9]   MATHEMATICAL-MODELS OF THE THERMAL-DECOMPOSITION OF COAL .2. SPECIFIC-HEATS AND HEATS OF REACTION [J].
MERRICK, D .
FUEL, 1983, 62 (05) :540-546
[10]   Carbon monoxide reduction and accompanying swelling of iron oxide compacts [J].
Nasr, MI ;
Omar, AA ;
Hessien, MM ;
ElGeassy, AA .
ISIJ INTERNATIONAL, 1996, 36 (02) :164-171