The production of hydrogen through the uncatalyzed partial oxidation of methane in an internal combustion engine

The thermodynamic and kinetic limitations of the uncatalyzed partial oxidation of methane for the production of synthesis gas, which is made up of mostly hydrogen and carbon monoxide in a variety of proportions, are reviewed. It is suggested that such processes can be made to proceed successfully in a conventional internal combustion engine when operated on excessively rich mixtures of methane and oxygenated air. This is achieved while simultaneously producing power and regenerative exhaust gas heating. Experimental results are described that show a dual fuel engine of the compression ignition type with pilot liquid fuel injection can be operated on excessively rich mixtures of methane and air supplemented with oxygen gas to produce hydrogen rich gas with high methane conversion rates. Similarly, a spark ignition engine was reported to be equally capable of such production and performance. it is shown that there are viable prospects for the simultaneous production of synthesis gas in engines with efficient useful mechanical power and exhaust gas regenerative heating. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.