Determination of antimony in sediments and soils by slurry sampling graphite furnace atomic absorption spectrometry using a permanent chemical modifier

For comparison of action of mixed permanent modifiers Ir/Nb and Ir/W, the influence of the amounts of modifier components was studied and the atomic absorption pyrolysis and atomization curves were determined with different modifiers. The optimum amounts of modifier components were 30 mu g Ir and 40 mu g of Nb that were deposited onto the L'vov platform in advance to analytical measurements. The long-term performance of the Ir and Nb permanent modifiers was derived from the investigations by scanning electron microscopy and energy dispersive X-ray spectrometry. The soil and sediment slurries were prepared in 4% hydrofluoric acid and 6% suspension of polytetrafluoroethylene in order to remove the high concentration of silica during the pyrolysis step of 900 degrees C. The calibration was made by using aqueous standards. The analysis of certified reference materials confirmed the accuracy and reliability of the proposed analytical approach. The precision of Sb determination was characterized with less than 6% RSD. (C) 2011 Elsevier B.V. All rights reserved.