Ni2+ substituted Mg-Cu-Zn ferrites by molten salt route: Evaluation of structural, morphological and electromagnetic properties

被引：17
作者：
Thorat, L. M. [1 ]
Patil, J. Y. [1 ]
Nadargi, D. Y. [1 ]
Kambale, R. C. [2 ]
Suryavanshi, S. S. [1 ]
机构：
[1] Solapur Univ, Sch Phys Sci, Solapur 413255, Maharashtra, India
[2] Savitribai Phule Pune Univ, Dept Phys, Pune 411007, Maharashtra, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2019年 / 99卷
关键词：
Ferrites; Molten salt; Magnetic materials; X-ray diffraction; TEM; TERT-BUTYLHYDROPEROXIDE; MAGNETIC-PROPERTIES; NANOPARTICLES; OXIDATION; COFE2O4; GREEN; MANGANESE(II); CYCLOHEXENE; COMPLEXES; NI(II);
D O I：
10.1016/j.inoche.2018.11.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report a facile molten salt route to synthesize Ni2+ substituted Mg-Cu-Zn spinel ferrites with their electromagnetic properties. The ferrite nanoparticles (Mg0.25-xNixCu0.25Zn0.5Fe2O4 with x = 0.0-0.25 in step 0.05) synthesized at 800 degrees C using sodium chloride as a growth inhibitor, revealed an excellent tuning in electromagnetic properties due to addition of Ni. Single-phase formation of spinel ferrite having crystallite size in the range of 45-49 nm was observed by XRD and confirmed by TEM/SAED spot pattern. The obtained dielectric and magnetic properties (high initial permeability = 592, saturation magnetization = 325 emu, coercivity = 36.86 G) of nanostructured spinel ferrite suggest the possibility of utilization of the developed material for MLCI application. The molten salt chemistry, and thereby its effect on structural, morphological and electromagnetic properties of Mg-Cu-Zn ferrites are discussed.
引用
收藏
页码：20 / 25
页数：6
相关论文
共 30 条
  • [1] Magnetic nickel ferrite nanoparticles: Green synthesis by Urtica and therapeutic effect of frequency magnetic field on creating cytotoxic response in neural cell lines
    Amiri, Mahnaz
    Pardakhti, Abbas
    Ahmadi-Zeidabadi, Meysam
    Akbari, Ahmad
    Salavati-Niasari, Masoud
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2018, 172 : 244 - 253
  • [2] Synthesis and in vitro evaluation of a novel magnetic drug delivery system; proecological method for the preparation of CoFe2O4 nanostructures
    Amiri, Mahnaz
    Akbari, Ahmad
    Ahmadi, Meysam
    Pardakhti, Abbas
    Salavati-Niasari, Masoud
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 2018, 249 : 1151 - 1160
  • [3] Removal of malachite green (a toxic dye) from water by cobalt ferrite silica magnetic nanocomposite: Herbal and green sol-gel autocombustion synthesis
    Amiri, Mahnaz
    Salavati-Niasari, Masoud
    Akbari, Ahmad
    Gholami, Tahereh
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (39) : 24846 - 24860
  • [4] Sol-gel auto-combustion synthesize and characterization of a novel anticorrosive cobalt ferrite nanoparticles dispersed in silica matrix
    Amiri, Mahnaz
    Salavati-Niasari, Masoud
    Akbari, Ahmad
    Razavi, Razie
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (14) : 10495 - 10508
  • [5] Caffeine: A novel green precursor for synthesis of magnetic CoFe2O4 nanoparticles and pH-sensitive magnetic alginate beads for drug delivery
    Amiri, Mahnaz
    Salavati-Niasari, Masoud
    Pardakhty, Abbas
    Ahmadi, Meysam
    Akbari, Ahmad
    [J]. MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2017, 76 : 1085 - 1093
  • [6] A magnetic CoFe2O4/SiO2 nanocomposite fabricated by the sol-gel method for electrocatalytic oxidation and determination of L-cysteine
    Amiri, Mahnaz
    Salavati-Niasari, Masoud
    Akbari, Ahmad
    [J]. MICROCHIMICA ACTA, 2017, 184 (03) : 825 - 833
  • [7] Synthesis and Characterization of Antibacterial Activity of Spinel Chromium-Substituted Copper Ferrite Nanoparticles for Biomedical Application
    Ansari, Mohammad Azam
    Baykal, Abdulhadi
    Asiri, Sara
    Rehman, Suriya
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (06) : 2316 - 2327
  • [8] Coble R.L., 1967, MAT SCI RES, V6, P423
  • [9] Modified single-phase hematite nanoparticles via a facile approach for large-scale synthesis
    Esmaeili, Elahe
    Salavati-Niasari, Masoud
    Mohandes, Fatemeh
    Davar, Fatemeh
    Seyghalkar, Hamideh
    [J]. CHEMICAL ENGINEERING JOURNAL, 2011, 170 (01) : 278 - 285
  • [10] PREPARATION OF ROD-SHAPED BATIO3 POWDER
    HAYASHI, Y
    KIMURA, T
    YAMAGUCHI, T
    [J]. JOURNAL OF MATERIALS SCIENCE, 1986, 21 (03) : 757 - 762
123