Bis{2-[3-(hydroxyimino-κN)butan-2-ylidene]-N-methylhydrazinecarbothioamide-κ2N2,S}nickel(II) dichloride

被引:1
作者
Abduelftah, Halema Shaban [1 ,2 ]
Ali, Amna Qasem [1 ,2 ]
Eltayeb, Naser Eltaher [1 ,3 ]
Teoh, Siang Guan [1 ]
Fun, Hoong-Kun [4 ]
机构
[1] Univ Sains Malaysia, Sch Chem Sci, Minden, Penang, Malaysia
[2] Sabha Univ, Fac Sci, Sabha, Libya
[3] Int Univ Africa, Dept Chem, Khartoum, Sudan
[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词
COMPLEXES;
D O I
10.1107/S1600536811055395
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Ni(C6H12N4OS)(2)]Cl-2, contains two independent Ni-II complex cations and four chloride anions. Each Ni-II ion is six-coordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds into infinite chains propagating along [10 (1) over bar]. Weak intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen bonds are also observed.
引用
收藏
页码:M108 / U313
页数:17
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