Bis{2-[3-(hydroxyimino-κN)butan-2-ylidene]-N-methylhydrazinecarbothioamide-κ2N2,S}nickel(II) dichloride

被引：1

作者：

Abduelftah, Halema Shaban ^{[1
,2
]}

Ali, Amna Qasem ^{[1
,2
]}

Eltayeb, Naser Eltaher ^{[1
,3
]}

Teoh, Siang Guan ^{[1
]}

Fun, Hoong-Kun ^{[4
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Sci, Minden, Penang, Malaysia

[2] Sabha Univ, Fac Sci, Sabha, Libya

[3] Int Univ Africa, Dept Chem, Khartoum, Sudan

[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

COMPLEXES;

D O I：

10.1107/S1600536811055395

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [Ni(C6H12N4OS)(2)]Cl-2, contains two independent Ni-II complex cations and four chloride anions. Each Ni-II ion is six-coordinated in a distorted octahedral geometry by four N atoms from the two imine and two oxime groups and two S atoms from the thione group. In the crystal, the cations and anions are linked through N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds into infinite chains propagating along [10 (1) over bar]. Weak intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen bonds are also observed.

引用

页码：M108 / U313

页数：17

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