Self-organization of gold nanoparticles on surface-modified conducting polymer films

被引:0
|
作者
Zhang, DH [1 ]
Klapman, S [1 ]
Hanks, TW [1 ]
机构
[1] Furman Univ, Dept Chem, Greenville, SC 29613 USA
来源
SELF-ASSEMBLED NANOSTRUCTURED MATERIALS | 2003年 / 775卷
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D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thiol-coated gold nanoparticles with a diameter of approximately 7.5 nanometers and a narrow particle distribution were prepared from sodium tetracbloroaurate under phase transfer conditions. The thiols used were 1-mercaptododecane (1) and 1-mercapto-9,11-heptadecadiyne (4). The particles were cast onto thin films of polyaniline and poly(3,4-ethylenedioxythiophene), as well as onto thiol-coated versions of the same polymer. Surface modification of the polymers with long chain thiols encourages the spontaneous self-assembly of the particles into two-dimensional arrays and may offer a unique method for stabilization of nanoparticle assemblies on polymer substrates.
引用
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页码:185 / 190
页数:6
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