Influence of the iron oxidation state on the nucleation of basalt glass

被引：0
作者：
Tosic, MB
Dimitrijevic, RZ
Radosavljevic, SA
Duricic, MA
机构：
[1] Inst Technol Nucl & Other Mineral Raw Mat, YU-11000 Belgrade, Yugoslavia
[2] Univ Belgrade, Fac Mining & Geol, YU-11000 Belgrade, Yugoslavia
来源：
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 1998年 / 63卷 / 12期
关键词：
glass; nucleation; iron effects;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The influence of the FeO/(FeO+Fe2O3) ratio on the nucleation of basalt glass was investigated. In the studied glasses, this ratio was 0.69 and 0.995. It was shown that at the ratio of 0.995 nucleation temperature was lower by 5 degrees C, the nucleation rate was lower by 13.4%, the crystallization activation energy was higher by 94 kJ/mol and the nucleation curve was narrower. Heterogeneous nucleation occurs in the investigated glasses. The same crystalline phase, monoclinic pyroxene-augite (Ca, Mg, Fe, Al)(Si,Al)(2)O-6 was developed during the controlled crystallization of glasses A and B.
引用
收藏
页码：1019 / 1030
页数：12
相关论文
共 50 条
  • [31] Effect of structural relaxation on crystal nucleation in a soda-lime-silica glass
    Rodrigues, Lorena R.
    Abyzov, Alexander S.
    Fokin, Vladimir M.
    Zanotto, Edgar Dutra
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2021, 104 (07) : 3212 - 3223
  • [32] NUCLEATION IN LITHIUM DISILICATE GLASS - A TEST OF CLASSICAL-THEORY BY QUANTITATIVE MODELING
    GREER, AL
    KELTON, KF
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (05) : 1015 - 1022
  • [33] Nucleation kinetics in a supercooled metallic glass former
    Puosi, F.
    Pasturel, A.
    ACTA MATERIALIA, 2019, 174 : 387 - 397
  • [34] Enhancing the temperature resistance of hybrid basalt/glass epoxy laminates
    Msangi, Innocent Chikira
    Liu, Jianxun
    Ma, Xinlei
    Ali, Sheeraz
    Khan, Jahan Zaib
    Wu, Zhishen
    POLYMER COMPOSITES, 2025,
  • [35] VITRIFICATION OF THE NUCLEAR 'SIMULATED' CESIUM WASTE BY USING BASALT GLASS
    Sezen, Gul Akdag
    Subasi, Metin
    SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI, 2011, 29 (01): : 43 - 51
  • [36] The Influence of Order on the Nucleation Barrier
    K. F. Kelton
    A. L. Greer
    D. M. Herlach
    D. Holland-Moritz
    MRS Bulletin, 2004, 29 : 940 - 944
  • [37] The influence of order on the nucleation barrier
    Kelton, KF
    Greer, AL
    Herlach, DM
    Holland-Moritz, D
    MRS BULLETIN, 2004, 29 (12) : 940 - 944
  • [38] Structural heterogeneity and homogeneous nucleation of 1BaO-2SiO2 glass
    Takahashi, Yoshihiro
    Osada, Minoru
    Masai, Hirokazu
    Fujiwara, Takumi
    APPLIED PHYSICS LETTERS, 2009, 94 (21)
  • [39] DETERMINING THE NUCLEATION RATE CURVE FOR LITHIUM DISILICATE GLASS BY DIFFERENTIAL THERMAL-ANALYSIS
    RAY, CS
    DAY, DE
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (02) : 439 - 442
  • [40] Nucleation thermodynamics of oxide during metal oxidation
    Zhou, Guangwen
    APPLIED PHYSICS LETTERS, 2009, 94 (20)
12345