Interaction of Xenon with Cucurbit[5]uril in Water

被引：33
作者：
Huber, Gaspard [1 ]
Legrand, Francois-Xavier [1 ]
Lewin, Veronique [2 ]
Baumann, Delphine [2 ]
Heck, Marie-Pierre [2 ]
Berthault, Patrick [1 ]
机构：
[1] CEA, IRAMIS, M SIS2, LSDRM,UMR CEA CNRS 3299, F-91191 Gif Sur Yvette, France
[2] CEA, DSV, iBiTec S, Serv Chim Biol & Marquage, F-91191 Gif Sur Yvette, France
来源：
CHEMPHYSCHEM | 2011年 / 12卷 / 06期
关键词：
cucurbiturils; host-guest systems; kinetics; NMR spectroscopy; xenon; NMR-BASED BIOSENSORS; CUCURBITURIL; STABILITY; GASES;
D O I：
10.1002/cphc.201100068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Xenon-cucurbituril binding: The smallest member of the cucurbituril family is able to slowly trap xenon in water even at room temperature with quite a high binding constant. At higher temperatures, the binding is weaker and the exchange kinetics higher, inducing potential applications for the reversible trapping of gases. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1053 / 1055
页数：3
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