Five co-ordination at platinum(II) in a water soluble tertiary phosphine complex:: crystal structure of [Pt(PTA)3(I)2]•CH3OH

被引：32

作者：

Otto, S ^{[1
]}

Roodt, A ^{[1
]}

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

five-coordinate platinum(II); crystal structure; water-soluble; PTA ligands; Tolman angle; stability constants;

D O I：

10.1016/S1387-7003(00)00194-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A five co-ordinate platinum(II) complex containing the water soluble 1,3,5-triaza-7-phosphaadamantane ligand (PTA) [Pt(PTA)(3)(I)(2)] (1), was characterised in the solid state and aqueous solution. A re-calculation of the Tolman cone angle for the PTA ligand, as well as preliminary equilibrium constants for the formation of 1, is given. (C) 2001 Published by Elsevier Science B.V. All rights reserved.

引用

页码：49 / 52

页数：4

共 20 条

[1] Intermolecular hydrogen•••metal interactions.: The crystal structure of {cis-[PdCl2(TPA)2]}2•H2O, a water-soluble palladium(II) tertiary phosphine complex [J].

Alyea, EC ;

Ferguson, G ;

Kannan, S .

CHEMICAL COMMUNICATIONS, 1998, (03) :345-346

[2] DECHLORINATION OF CIPET2 BY (NP3)PT(PPH3) (NP3 = N(CH2CH2PPH2)3) - SYNTHESIS AND CHARACTERIZATION OF [(NP3)PT(PET2)](BPH4) AND [(NP3)PT(PHET2)](BPH4)2 [J].

CECCONI, F ;

GHILARDI, CA ;

MIDOLLINI, S ;

MONETI, S ;

ORLANDINI, A ;

SCAPACCI, G .

INORGANICA CHIMICA ACTA, 1991, 189 (01) :105-110

[3] TERMINAL ARSENIDO-PALLADIUM(II) AND PLATINUM(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF [(N(CH2CH2PPH2)3)PTASPH2]BPH4 [J].

CECCONI, F ;

GHILARDI, CA ;

MIDOLLINI, S ;

MONETI, S ;

ORLANDINI, A ;

SCAPACCI, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (22) :1583-1584

[4] PYRAMIDAL 5-CO-ORDINATION WITH FLATTENED TETRAHEDRAL BASAL BONDS - CRYSTAL AND MOLECULAR-STRUCTURES OF DIBROMOTRIS-(5-ETHYL-5H-DIBENZO-PHOSPHOLE)PALLADIUM(II)-CHLOROBENZENE,DIBROMOTRIS-(5-ETHYL-5H-DIBENZOPHOSPHOLE)PLATINUM(II)-BROMOBENZENE, AND DIBROMOTRIS-(5-METHYL-5H-DIBENZOPHOSPHOLE)PLATINUM(II)-BROMOBENZENE [J].

CHUI, KM ;

POWELL, HM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (17) :1879-1889

[5] CONSTITUTION OF COMPLEX METALLIC SALTS .19. 2-PHENYLISOPHOSPHINDOLINE DERIVATIVES OF PLATINUM(2) PALLADIUM)2) + NICKEL)2) [J].

COLLIER, JW ;

MANN, FG ;

WATSON, DG ;

WATSON, HR .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (MAY) :1803-+

[6]

DAIGLE D, 1974, J HETEROCYCLIC CHEM, V14, P1217

[7] Water-soluble organometallic compounds. 7. Further studies of 1,3,5-triaza-7-phosphaadamantane derivatives of group 10 metals, including metal carbonyls and hydrides [J].

Darensbourg, DJ ;

Robertson, JB ;

Larkins, DL ;

Reibenspies, JH .

INORGANIC CHEMISTRY, 1999, 38 (10) :2473-2481

[8] Water-soluble organometallic compounds .6. Synthesis, spectral properties, and crystal structures of complexes of 1,3,5-triaza-7-phosphaadamantane with group 10 metals [J].

Darensbourg, DJ ;

Decuir, TJ ;

Stafford, NW ;

Robertson, JB ;

Draper, JD ;

Reibenspies, JH .

INORGANIC CHEMISTRY, 1997, 36 (19) :4218-4226

[9] SYNTHESIS AND SPECTRAL PROPERTIES OF METAL-CARBONYL DERIVATIVES OF TETRABASIC, NONCHELATING PHOSPHATRIAZAADAMANTANE LIGAND [J].

DARENSBOURG, MY ;

DAIGLE, D .

INORGANIC CHEMISTRY, 1975, 14 (05) :1217-1218

[10] MOLECULAR-STRUCTURE AND SPECTRAL PROPERTIES OF PHOSPHATRIAZAADAMANTANEMOLYBDENUM PENTACARBONYL COMPLEX [J].

DELERNO, JR ;

TREFONAS, LM ;

DARENSBOURG, MY ;

MAJESTE, RJ .

INORGANIC CHEMISTRY, 1976, 15 (04) :816-819

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