Reactive and Organosoluble Anatase Nanoparticles by a Surfactant-Free Nonhydrolytic Synthesis

被引:23
作者
Aboulaich, A. [1 ]
Boury, B. [1 ]
Mutin, P. H. [1 ]
机构
[1] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, UMR CNRS 5253, UM2 ENSCM UM1,CC1701, F-34095 Montpellier 5, France
关键词
VERSATILE REACTION SYSTEM; SOL-GEL ROUTES; NONAQUEOUS SYNTHESIS; LOW-TEMPERATURE; TITANIUM-DIOXIDE; BENZYL ALCOHOL; METAL; SEMICONDUCTOR; NANOCRYSTALS; CRYSTALLINE;
D O I
10.1021/cm101191a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Unaggregated anatase nanoparticles with controlled sizes are obtained by non hydrolytic reaction of titanium(IV) chloride with a stoichiometric amount of diisopropyl ether, in the absence of surfactant or coordinating solvent. The nanoparticles can be modified by a phosphonic acid or can form monolayers by reaction with an hydroxylated substrate. © 2010 American Chemical Society.
引用
收藏
页码:4519 / 4521
页数:3
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