Core-shell structuredCsPbBr3/Sn-TiO2 nanocrystals for visible-light-driven photocatalyst in aqueous solution

All-inorganic perovskite materials have attracted much attention in the field of photocatalysts due to their unique photoelectric properties.However, the inherent poor stability of perovskite quantum dots significantlyhinders their practical applications. Herein, to settle the instabilities of inorganic perovskite materials, Sn-TiO2 coated CsPbBr3 quantum dots named CsPbBr3/Sn-TiO2, are fabricated via resaturated recrystallization, sol-gel coating and solvothermal crystallization.The XRD results demonstrated that the core-shell structure of CsPbBr3/Sn-TiO2 nanocrystals was successfully synthesized.Moreover, excellent dispersion is verified for CsPbBr3/Sn-TiO3 nano -crystals with a core-shell structure by TEM. The particle size of CsPbBr3/Sn-TiO2 nanocrystals is 15-30 nm, where the core size for CsPbBr3 quantum dots is 4-8 nm, and the Sn-TiO2 shell thickness is 2-8 nm.The pho-tocatalytic activity of nanocomposites was studied by the photodegradation of RhB aqueous solution under the irradiation of 100 mWcm(-2) air mass 1.5 global AM1.5G sunlight. Compared with traditional photocatalyst P25, the core-shell structured CsPbBr3/Sn-TiO2 nanocrystals exhibited better photocatalytic performance, with a degradation efficiency of 96.6% and a degradation rate constant of 10.68 x 10(-2) min(-1) in 30 min of catalytic time, which was five times higher than that of P25.The core-shell structured CsPbBr3/Sn-TiO2 nanocrystals have long-term stability in water system and have potential practical application value in the field of environmental governance.