A highly water-soluble zinc(II) phthalocyanines as potential for PDT studies: Synthesis and characterization

被引：21

作者：

Baygu, Yasemin ^{[1
]}

Gok, Yasar ^{[2
]}

机构：

[1] Pamukkale Univ, Dept Chem, Kiralik Denizli, Turkey

[2] Usak Univ, Dept Chem Engn, Usak, Turkey

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 96卷

关键词：

Zinc phthalocyanine; Cyclotetramerization; Click reaction; PDT; Red shift; Detosylation; PHOTODYNAMIC THERAPY; METAL-FREE; PERIPHERAL POSITIONS; AGGREGATION BEHAVIOR; MAIN ABSORPTION; 1000; NM; PHOTOSENSITIZERS; COMPLEXES; MACROCYCLES; METALLOPHTHALOCYANINES;

D O I：

10.1016/j.inoche.2018.08.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New zinc(II) phthalocyanines cotaining octa triazole linked tetraethylene glycol derived from peripheral or non-peripheral bis-{3-[4-(2-12-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy)-ethoxymethyl]-[1,2,3] triazol-1-yl]-propylsulfanyl}-phthalonitriles (9, 12) have been synthesized by multi-step reaction sequence and characterized. Phthalonitriles have been prepared by the reaction of 3,6-bis(3-azido-propylsulfanyl) phthalonitrile (7) or 4,5-bis(3-azido-propylsulfanyl)phthalonitrile (II). The new water-soluble zinc (II) phthalocyanines were synthesized by the tetramerization reaction of substituted dicarbodinitrile compounds. Singlet oxygen quantum yields of the complexes have been determined. These new compounds have been characterized by a combination of elemental analysis, FT-IR,H- 1 and C-13 NMR, MS spectrometer and UV-vis spectrophotometer techniques.

引用

页码：133 / 138

页数：6

共 58 条

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