Quantitative analysis of CO-humidity gas mixtures with self-heated nanowires operated in pulsed mode

被引:25
作者
Prades, J. D. [1 ]
Hernandez-Ramirez, F. [1 ,2 ]
Fischer, T. [3 ]
Hoffmann, M. [3 ]
Mueller, R. [3 ]
Lopez, N. [4 ]
Mathur, S. [3 ]
Morante, J. R. [1 ,2 ]
机构
[1] Univ Barcelona, Dept Elect, E-08028 Barcelona, Spain
[2] Inst Recerca Energia Catalunya IREC, Barcelona 08019, Spain
[3] Univ Cologne, Inst Inorgan Chem, D-50939 Cologne, Germany
[4] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain
关键词
TIN OXIDE; SNO2; NANOWIRES; ELECTRONIC NOSE; WATER-VAPOR; SENSORS; TEMPERATURE; OXYGEN; NANOSTRUCTURES; SELECTIVITY; SURFACE;
D O I
10.1063/1.3515918
中图分类号
O59 [应用物理学];
学科分类号
摘要
Self-heating effect in individual metal oxide nanowires can be used to activate their response to gases with power consumptions below tenths of microwatts. The thermal response time of these devices is extremely fast (a few milliseconds) and it makes it possible to observe the kinetics of the interactions between the gas molecules and the metal oxide. In this work we demonstrate that such effects enable an experimental methodology to improve the selectivity of metal oxide-based sensors based on the analysis of their fast response dynamics. Specifically, this work jointly analyzes the magnitude and response time of SnO2 nanowire-based sensors to carbon monoxide (CO) and humidity (H2O) mixtures, proving that a quantitative analysis of CO-H2O gas blends can be achieved by modulating their work temperature through the self-heating effect. (C) 2010 American Institute of Physics. [doi:10.1063/1.3515918]
引用
收藏
页数:3
相关论文
共 53 条
[1]   Optimization of tin dioxide nanosticks faceting for the improvement of palladium nanocluster epitaxy [J].
Arbiol, J ;
Cirera, A ;
Peiró, F ;
Cornet, A ;
Morante, JR ;
Delgado, JJ ;
Calvino, JJ .
APPLIED PHYSICS LETTERS, 2002, 80 (02) :329-331
[2]   Metal oxide-based gas sensor research: How to? [J].
Barsan, N. ;
Koziej, D. ;
Weimar, U. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 121 (01) :18-35
[3]  
Bârsan N, 2003, J PHYS-CONDENS MAT, V15, pR813, DOI 10.1088/0953-8984/15/20/201
[4]   The surface and materials science of tin oxide [J].
Batzill, M ;
Diebold, U .
PROGRESS IN SURFACE SCIENCE, 2005, 79 (2-4) :47-154
[5]   Metal oxide nanowires as chemical sensors [J].
Comini, E. ;
Sberveglieri, G. .
MATERIALS TODAY, 2010, 13 (7-8) :28-36
[6]   Quasi-one dimensional metal oxide semiconductors: Preparation, characterization and application as chemical sensors [J].
Comini, E. ;
Baratto, C. ;
Faglia, G. ;
Ferroni, M. ;
Vomiero, A. ;
Sberveglieri, G. .
PROGRESS IN MATERIALS SCIENCE, 2009, 54 (01) :1-67
[7]   Calibration of microhotplate conductometric gas sensors by non-linear multivariate regression methods [J].
Dable, BK ;
Booksh, KS ;
Cavicchi, R ;
Semancik, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 101 (03) :284-294
[8]   Development of ultra-low-power consumption MOX sensors with ppb-level VOC detection capabilities for emerging applications [J].
Elmi, I. ;
Zampolli, S. ;
Cozzani, E. ;
Mancarella, F. ;
Cardinali, G. C. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 135 (01) :342-351
[9]   Selectivity in high-temperature operated semiconductor gas-sensors [J].
Fleischer, M ;
Meixner, H .
SENSORS AND ACTUATORS B-CHEMICAL, 1998, 52 (1-2) :179-187
[10]   CO sensing with SnO2 thick film sensors:: role of oxygen and water vapour [J].
Hahn, SH ;
Bârsan, N ;
Weimar, U ;
Ejakov, SG ;
Visser, JH ;
Soltis, RE .
THIN SOLID FILMS, 2003, 436 (01) :17-24