Reaction progress kinetic analysis: A powerful methodology for mechanistic studies of complex catalytic reactions

被引：554

作者：

Blackmond, DG ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 28期

关键词：

catalysis; in situ measurements; kinetics; reaction kinetics; reaction mechanisms;

D O I：

10.1002/anie.200462544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction progress kinetic analysis to obtain a comprehensive picture of complex catalytic reaction behavior is described. This methodology employs in situ measurements and simple manipulations to construct a series of graphical rate equations that enable analysis of the reaction to be accomplished from a minimal number of experiments. Such an analysis helps to describe the driving forces of a reaction and may be used to help distinguish between different proposed mechanistic models. This Review describes the procedure for undertaking such analysis for any new reaction under study. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4302 / 4320

页数：19

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